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The correct roder o fincreasing C-O bond...

The correct roder o fincreasing `C-O` bond lengths in `CO, CO_3^(2-)` and ` CO_2` is :

A

`CO_3^(2-) gt CO_2 gt CO`

B

`CO_2 gt CO_3^(2-) gt CO`

C

`CO gt CO_3^(2-) gt CO_2`

D

`CO gt CO_2 gt CO_3^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
D

Bond order for` CO,CO_2` and `CO_3^(2-)` are `3,2` and `1.33` . Higher is bond order lesser in bond length. Also `C` is `CO_3^(2-)` is ` sp^2`-hybridsed , in ` CO_2` sp-hybridized . Thus more is s-character , more is overlapping shorter will be bond .
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P BAHADUR-CHEMICAL BONDING-Exercise2A
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  4. Among the following which has resonating structure ?

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  10. N -O -N bond andle is maximum in :

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  11. Which is not a permissible resonating structure ?

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  12. Which pair represents canonical from ?

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  13. Which of the following would have permanent dipple moment ?

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