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PCl5 in solid state exists as PCl4^+ and...

`PCl_5` in solid state exists as `PCl_4^+` and `PCl_6^-` Also in some solvents it undergoes dissoctation as `2PCl_5 hArr PCl_2^+ +PCl_6^-`.
The oxidation number of `P` in `PCl_5 .PCl_4^+ ` and `PCl_6^-` are respectively :

A

` 5, 4,4`

B

`5 ,5,5`

C

` 4,5,5`

D

` 4,4,4`

Text Solution

Verified by Experts

The correct Answer is:
B
Each has ` + 5` oxidation state
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P BAHADUR-CHEMICAL BONDING-Exercise 6
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  2. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  3. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  4. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  5. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  6. PCl5 in solid state exists as PCl4^+ and PCl6^- Also in some solvents ...

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  7. Lewis concept of covalency of an element involved octet rule .Later o...

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  8. Lewis concept of covalency of an element involved octet rule .Later o...

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  9. Lewis concept of covalency of an element involved octet rule .Later o...

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  10. Lewis concept of covalency of an element involved octet rule .Later o...

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  11. Lewis concept of covalency of an element involved octet rule .Later o...

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  12. Lewis concept of covalency of an element involved octet rule .Later o...

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  13. Lewis concept of covalency of an element involved octet rule .Later o...

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  14. Lewis concept of covalency of an element involved octet rule .Later o...

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  15. To explain the abnormality in some molecules , the conecpt of H-bondin...

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  16. To explain the abnormality in some molecules , the conecpt of H-bondin...

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  17. To explain the abnormality in some molecules , the conecpt of H-bondin...

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  18. To explain the abnormality in some molecules , the conecpt of H-bondin...

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  19. To explain the abnormality in some molecules , the conecpt of H-bondin...

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