Home
Class 12
CHEMISTRY
The thermal decomposition of N(2)O(5) oc...

The thermal decomposition of `N_(2)O_(5)` occurs in the following steps:
Step I: `N_(2)O_(5) overset("slow")(rarr) NO_(2)+NO_(3)`
Step II: `N_(2)O_(5)+NO_(3)overset("fast")(rarr)3NO_(2)+O_(2)`
Overall reaction, `2N_(2)O_(5)rarr 4NO_(2)+O_(2)`
Suggest the rate expression.

Text Solution

Verified by Experts

Rate `=K[N_(2)O_(5)].` (from slow step)
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    P BAHADUR|Exercise Exercise 1|2 Videos
  • CHEMICAL KINETICS

    P BAHADUR|Exercise Exercise 3A|2 Videos
  • DILUTE SOLUTION AND COLLIGATIVE PROPERTIES

    P BAHADUR|Exercise Exercise 9 Advanced Numerical|12 Videos

Similar Questions

Explore conceptually related problems

For the first order reaction 2N_(2)O_(5)(g) rarr 4NO_(2)(g) + O_(2)(g)

NH_(4)NO_(3) overset(Delta) to N_(2)O+H_(2)O

NO+NO_(2) overset(-11^(@)C) to N_(2)O_(3)

N_(2)O_(3) overset(R.T.) to NO+NO_(2)

Thermal decomposition of N_2O_5 occurs as per the equation below 2N_2O_5rarr4NO_2+O_2 The correct statement is

Out of the following redox reactions I. NH_(4)NO_(3)overset(Delta ) ( rarr) N_(2)O + 2H_(2)O II. NH_(4)NO_(2) overset( Delta)(rarr)N_(2) + 2H_(2)O III. PCl_(5) overset(Delta ) ( rarr) PCl_(3) + Cl_(2) disproportionation is not shown in

The depletion of ozone involves the following steps : Step 1 : O_3underset(K_1)overset(K_2)hArrO_2+O (fast) Step 2 : O_3+Ounderset(K)rarr2O_2 (slow) The predicted order of the reaction will be

The reaction f NO_(2)(g) and O_(3)(g) is first-order in NO_(2) and O_(3)(g) 2NO_(2)(g) +O_(3)(g) rarr N_(2)O_(5)(g) + O_(2)(g) The reaction can take place by mechansim: (P) NO_(2)+O_(3) overset("slow") rarr NO_(3)+O_(2) NO_(3)+NO_(2) overset("fast")rarr N_(2)O_(5) (Q) O_(3)underset(k_(b)) overset(k_(a) "fast")hArr O_(2)+[O] NO_(2) +O overset("slow")rarr NO_(3) NO_(3) +NO_(2) overset("fast")rarr N_(2)O_(5) Select the correct mechanism.