Home
Class 12
CHEMISTRY
A certain endothermic reaction: Ararr Pr...

A certain endothermic reaction: `Ararr` Product, `DeltaH=+ve` proceeds in a sequence of three elementary steps with the rate constants `K_(1), K_(2)` and `K_(3)` and each one having energy of activation `E_(a), E_(2)` and `E_(3)` respectively at `25^(@)C`. The observed rate constant for the reaction is equal to `K_(3) sqrt(K_(1)/K_(2)). A_(1), A_(2)` and `A_(3)` are Arrhenius parameters respectively.
The observed Arrhenius parameter for the reaction is:

A

(a) `(2A_(1)-A_(2)+2A_(3))/(2)`

B

(b) `sqrt(A_(1)/A_(2)).A_(3)`

C

(c ) `A_(1)A_(2)A_(3)`

D

(d) `(A_(1).A_(3))/(A_(2))`

Text Solution

Verified by Experts

The correct Answer is:
b
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    P BAHADUR|Exercise Exercise 1|2 Videos
  • CHEMICAL KINETICS

    P BAHADUR|Exercise Exercise 3A|2 Videos
  • DILUTE SOLUTION AND COLLIGATIVE PROPERTIES

    P BAHADUR|Exercise Exercise 9 Advanced Numerical|12 Videos

Similar Questions

Explore conceptually related problems

A certain endothermic reaction: Ararr Product, DeltaH=+ve proceeds in a sequence of three elementary steps with the rate constants K_(1), K_(2) and K_(3) and each one having energy of activation E_(a), E_(2) and E_(3) respectively at 25^(@)C . The observed rate constant for the reaction is equal to K_(3) sqrt(K_(1)/K_(2)). A_(1), A_(2) and A_(3) are Arrhenius parameters respectively. The observed energy of activation for the reaction is:

A certain endothermic reaction: Ararr Product, DeltaH=+ve proceeds in a sequence of three elementary steps with the rate constants K_(1), K_(2) and K_(3) and each one having energy of activation E_(a), E_(2) and E_(3) respectively at 25^(@)C . The observed rate constant for the reaction is equal to K_(3) sqrt(K_(1)/K_(2)). A_(1), A_(2) and A_(3) are Arrhenius parameters respectively. Which represents the correct value, if catalyst is not present?

A certain endothermic reaction: Ararr Product, DeltaH=+ve proceeds in a sequence of three elementary steps with the rate constants K_(1), K_(2) and K_(3) and each one having energy of activation E_(a), E_(2) and E_(3) respectively at 25^(@)C . The observed rate constant for the reaction is equal to K_(3) sqrt(K_(1)/K_(2)). A_(1), A_(2) and A_(3) are Arrhenius parameters respectively. If temperature coefficient of the observed reaction is 2 , the numerical value of E_(1)-E_(2)+2E_(3) is:

A certain endothermic reaction: Ararr Product, DeltaH=+ve proceeds in a sequence of three elementary steps with the rate constants K_(1), K_(2) and K_(3) and each one having energy of activation E_(a), E_(2) and E_(3) respectively at 25^(@)C . The observed rate constant for the reaction is equal to K_(3) sqrt(K_(1)/K_(2)). A_(1), A_(2) and A_(3) are Arrhenius parameters respectively. Presence of a catalyst decreases the energy of activation of each path by half the value of E_(1) . Assuming the order actors same, the observed energy of activation would be:

A certain endothermic reaction: Ararr Product, DeltaH=+ve proceeds in a sequence of three elementary steps with the rate constants K_(1), K_(2) and K_(3) and each one having energy of activation E_(a), E_(2) and E_(3) respectively at 25^(@)C . The observed rate constant for the reaction is equal to K_(3) sqrt(K_(1)/K_(2)). A_(1), A_(2) and A_(3) are Arrhenius parameters respectively. For a reversible reaction, A underset(K_(2))overset(K_(1))(hArr) B, DeltaH=q , if perexponential factors are same. The correct relation is:

For a reaction taking place in three steps, the rate constant are k_(1), k_(2) and k_(3) and overall rate constant is k=(k_(1)k_(3))/(k_(2) . If the energies of activation E_(1) , E_(2) and E_(3) are 60, 30 and 10 kJ mol^(-1) respectively, then the overall energy of activation is:

A reaction taking place at "T K" involves three elementary steps having rate constants "K"_(1), "K"_(2) and "K"_(3) and energy of activation 40, 30 and 20kJ respectively.If overall rate constant K=(K_(1)K_(3))/(K_(2)) , then overall energy of activation will be : ( Assume frequency factor "A" be same for all elementary steps ).

A reaction takes place in three steps. The rate constant are k_(1), k_(2) and k_(3) . The overall rate constant k=(k_(1)k_(3))/(k_(2)) . If E_(1), E_(2) and E_(3) (energy of activation) are 60, 30 and 10 kJ, respectively, the overall energy. Of activation is