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The activity of a catalyst has been expl...

The activity of a catalyst has been explained in terms of spontaneous adsorption of reactant moleculse on the surface of catlyst and ther by forming an activated adsorbed complex along with evolution of heat. The adorbed activated complex undergoes to decompositio to regencerate catlyst and give products . adorpton is of two types :
(i) Physical adsorptio due to van der Waal's forces of attraction between reactant and catalyst molecules , weak , less exothermic, mulitlay and non-dirctional .
(ii) Chemical dasorpton due to free valencies , strong, more exothermic, unilayer. The extent of adormpotion `( x//m)` vs temperature at constant pressure gives isobars. Freundilish studied influence of pressure on the phusical adorptons and reported that log `x/m log K + 1/n log P`.
The extent of adsroptong depends on :

A

nature and surface area of adsorbent

B

nature and conceteation of adorbate

C

temperature

D

all of these

Text Solution

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The correct Answer is:
d

All are facts .
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The activity of a catalyst has been explained in terms of spontaneous adsorption of reactant moleculse on the surface of catlyst and ther by forming an activated adsorbed complex along with evolution of heat . The adorbed activated complex undergoes to decompositio to regencerate catlyst and give products . adorpton is of two types : (i) Physical adsorptio due to van der Waal's forces of attraction between reactant and catalyst molecules , weak , less exothermic, mulitlay and non-dirctional . (ii) Chemical dasorpton due to free valencies , strong, more exothermic, unilayer. The extent of adormpotion ( x//m) vs temperature at constant pressure gives isobars. Freundilish studied influence of pressure on the phusical adorptons and reported that log x/m log K + 1/n log P . Select the correct staements .

The activity of a catalyst has been explained in terms of spontaneous adsorption of reactant moleculse on the surface of catlyst and ther by forming an activated adsorbed complex along with evolution of heat . The adorbed activated complex undergoes to decompositio to regencerate catlyst and give products . adorpton is of two types : (i) Physical adsorptio due to van der Waal's forces of attraction between reactant and catalyst molecules , weak , less exothermic, mulitlay and non-dirctional . (ii) Chemical dasorpton due to free valencies , strong, more exothermic, unilayer. The extent of adormpotion ( x//m) vs temperature at constant pressure gives isobars. Freundilish studied influence of pressure on the phusical adorptons and reported that log x/m log K + 1/n log P . During adorption of reactant momecules on catalyst surface :

The activity of a catalyst has been explained in terms of spontaneous adsorption of reactant moleculse on the surface of catlyst and ther by forming an activated adsorbed complex along with evolution of heat . The adorbed activated complex undergoes to decompositio to regencerate catlyst and give products . adorpton is of two types : (i) Physical adsorptio due to van der Waal's forces of attraction between reactant and catalyst molecules , weak , less exothermic, mulitlay and non-dirctional . (ii) Chemical dasorpton due to free valencies , strong, more exothermic, unilayer. The extent of adormpotion ( x//m) vs temperature at constant pressure gives isobars. Freundilish studied influence of pressure on the phusical adorptons and reported that log x/m log K + 1/n log P . The graph platted between log x/m vs log P was found to be a straight line . The slope and intercept of line leass for 1/n and log K values . find the wrong statement .

The van der waals forces are the greater in

Van der waals forces consist of

The van der waals forces are the greatest in

Which is correct in case of van der Waals adsorption?