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Classically, an electron can be in any o...

Classically, an electron can be in any orbit around the nucleus of an atom. Then what determines the typical atomic size? Why is an atom not, say, thousand times bigger than its typical size? The question had greatly puzzled Bohr before he arrived at his famous model of the atom that you have learnt in the text. To simulate what he might well have done before his discovery, let us play as follows with the basic constants of nature and see if we can get a quantity with the dimensions of length that is roughly equal to the known size of an atom `(~ 10^(–10)m)`.
(a) Construct a quantity with the dimensions of length from the fundamental constants e, `m_(e)`, and c. Determine its numerical value.
(b) You will find that the length obtained in (a) is many orders of magnitude smaller than the atomic dimensions. Further, it involves c. But energies of atoms are mostly in non-relativistic domain where c is not expected to play any role. This is what may have suggested Bohr to discard c and look for ‘something else’ to get the right atomic size. Now, the Planck’s constant h had already made its appearance elsewhere. Bohr’s great insight lay in recognising that h, `m_(e)`, and e will yield the right atomic size. Construct a quantity with the dimension of length from h, `m_(e)`, and e and confirm that its numerical value has indeed the correct order of magnitude.

Text Solution

Verified by Experts

(a) Using fundamental constants, e,`m_e` and c, we construct a quantity which has the dimenstions of length. This quantity is `((e^2)/(4pi in_0m_ec^2))`
Now, `(e^2)/(4pi in_0m_ec^2)=((1.6xx10^(-19))^2xx9xx10^9)/(9.1xx10^(-31)(3xx10^8)^2)=2.82xx10^(-15)m`
This is much smaller than the typical atomic size.
(b) However, when we drop c and use h,`m_e` and e to construct a quantity, which has dimensions of length, the quantity we obtain is `(4pi in_0(h//2pi)^2)/(m_e e^2)`
Now, `(4pi in_0(h//2pi)^2)/(m_e e^2)=((6.6xx10^(-34)//2pi)^2)/(9xx10^9xx(9.1xx10^(-31))(1.6xx10^(-19))^2)~~0.53xx10^(-10)m`
This is of the order of atomic sizes.
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Knowledge Check

  • An electron orbiting around the nucleus of an atom

    A
    has a magnetic dipole moment
    B
    exerts an electric force on the nucleus equal to that on it by the nucleus
    C
    does produce a magnetic induction at the nucleus
    D
    has a net energy inversely proportional to its distance from the nucleus.
  • Rutherford assumed in his atomic model that

    A
    the mass is concentrated at the center.
    B
    charge is concentrated at the center.
    C
    both the mass and charge are concentrated at the center.
    D
    electrons are positively charged particles.
  • Bohr's model of an atom can explain

    A
    only the spectrum of hydrogen atom
    B
    only spectrum of an atom or ion containing one electron
    C
    spectrum of hydrogen molecule
    D
    the solar spectrum
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