In the Angular process as atom makes a transition to a lower state without emitting a photon. The excess energy is transferred to an outer electron which may be ejected by the atom. (this is called an Augar elecrons ) . Assuming the nuclesu to be massive , calculate the kinetic energy of an `n=4` Augar electron emitted by chromium by absorbing the energy from a `n=2` to `n=1` transition .
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As the nucleus is massive, recoil momentum of the atom can be ignored. We can assume that the entire energy of transition is transferred to the Auger electron. As there is a single valence electron in chromium (Z=24), the energy states may be thought of as given by Bohr model. The energy of the nth state is `E_(n)=-(RZ^(2))/(n^(2))` where R is Rydberg constant. In the transition form n=2 to n=1, energy released, `DeltaE=-RZ^(2)(1/4-1)=3/4RZ^(2)` The energy required to ejected a n=4 electron `=RZ^(2)xx(1/4)^(2)=(RZ^(2))/16` `:.` KE a Auger electron=`(3RZ^(2))/4-(RZ^(2))/16` `KE=RZ^(2)(3/4-1/16)=11/16 RZ^(2)=11/16(13.6eV)xx24xx24=5385.6 eV`