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A mixture of ethyl iodide and m-propyl i...

A mixture of ethyl iodide and m-propyl iodide is subjected to Wurtz reaction. The hydrocarbon that will not be formed is

A

n-butane

B

n-propane

C

n-pentane

D

n-hexane

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The correct Answer is:
A
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Wurtz reaction involves the comdensation of two molecules of alkyl halides in the presence of sodium and dry ether R-X+2Na+R-Xoverset("dry ether")toR-R+2NaX In this reaction small amount of alkene is also formed as by product. CH_(3)CH_(2)Br+CH_(3)CH_(2)Broverset("Na/dry ether")toCH_(3)-CH_(2)-CH_(2)-CH_(3)+underset("By-product")ubrace(CH_(2)=CH_(2)+CH_(3)-CH_(3)) Tertiary alkyl halides do not give wurtz reaction. Frankland reaction is similar but has certain advantages over wurtz reaction. it is useful in the synthesis of symmetrical alkanes. frankland reaction is shown by primary, Secondary as well as tertiary alkyl halide. Q. A mixture of ethyl iodide and methyl iodide is subjected to wurtz reaction. the product that will not formed is

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MARVEL PUBLICATION-ALKANES-TEST YOUR GRASP
  1. To prepare a pure hexane the solution of any one of the following subs...

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  2. A haloalkane can be reduced to an alkane with the help of HI in presen...

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  3. 2-Brumo butane when treated with Na in the presence of dry ether gives

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  4. Which of the following will not give pure propane?

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  5. The conversation of liquid hydrocarbon into a mixture of gaseous compo...

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  6. Which of the following is not linked with methane?

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  7. For preparing an alkane a concentrated aqueous solution of sodium or p...

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  8. Among the paraffins it is generally found that with an increase in the...

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  9. Cyclohexane floats on water because

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  10. LPG is mixture of

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  11. During photochemical halogenation of alkanes the halogen molecules fir...

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  12. In the chlorination of alkanes, the correct order of reactivity of pri...

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  13. What is the chief product obtained when n-butane is treated with Br(2)...

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  14. In case of homologous series of alkanes, which one of the following st...

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  15. An alkane forms isomers if the number of carbon atoms is

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  16. Reduction of CH3COCH3 produces

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  17. A mixture of ethyl iodide and m-propyl iodide is subjected to Wurtz re...

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  18. Which is not correct in case of isopentane?

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  19. Which of the following statements is not correct?

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  20. Which one of the following does not give alkane?

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