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The possible mechanism for the reaction ...

The possible mechanism for the reaction
`2NO + 2H_(2) to N_(2) + 2H_(2)O` is
i) `2NO ltimplies N_(2)O_(2)`
ii) `N_(2)O_(2) + H_(2) overset("slow")to N_(2)O+H_(2)O`
iii) `N_(2)O + H_(2)O overset("fast")to N_(2) + H_(2)O`
a) What is rate law for the reaction?
b) What is the order of the reaction?

A

Rate =`[N_(2)O_(2)],"order"=1`

B

Rate`=[N_(2)O_(2)][H_(2)][H_(2)]"order"=2`

C

Rate `=[N_(2)O_(2)]^(2),"order"=2`

D

Rate `=[N_(2)O_(2)]^(2),"order"=3`

Text Solution

Verified by Experts

The correct Answer is:
B

The slowest step of the reaction is rate determining step `N_(2)O_(2) +H_(2)to N_(2)O+H_(2)O`
Rate of reaction ` =[N_(2)O][H_(2)]`
hence order og reaction = 2
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The possible mechanism for the reaction 2NO + 2H_(2) to N_(2) + 2H_(2)O is i) 2NO ltimplies N_(2)O_(2) ii) N_(2)O_(2) + H_(2) overset("slow")to N_(2)O+H_(2)O iii) N_(2)O + H_(2) overset("fast")to N_(2) + H_(2)O a) What is rate law for the reaction? b) What is the order of the reaction?

For a reaction, 2NO + 2H_(2) to N_(2) + 2H_(2) O , the possible mechanism is NO hArr N_(2)O_(2) N_(2)O_(2) + H_(2) overset("Slow")(to) N_(2)O + H_(2) O N_(2) O + H_(2) O overset("fast")(to) N_(2) + H_(2) O What is the rate law and order of the reaction?

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