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In case of nitrogen, NCl(3) is possible ...

In case of nitrogen, `NCl_(3)` is possible but not `NCl_(5)` while in case of phosphorous, `PCl_(5)` are possible. It is due to

A

availability of vacant d orbitals in P but not in N

B

lower electronegativity of P than N

C

lower tendency of H - bond formation in P than N

D

occurrence of P in solid while N in gaseous state at room temperature

Text Solution

Verified by Experts

The correct Answer is:
A

N does not have d-orbital `(1s^2 2s^2 2p^3)`
whereas P have d-orbital `(1s^2 2s^2 2p^6 3s^2 3p^3)`
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