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Arrange the following in increasing valu...

Arrange the following in increasing value of magnetic moments.
(i) `[Fe(Cn)_6]^(4-)` (ii) ` [Fe(CN)_6]^(3-)`
(iii) `[Cr(NH_3)_6]^(3+)` (iv) `[Ni(H_2O)_4]^(2+)`

A

(i) lt (ii) lt (iii) lt (iv)

B

(i) lt (ii) lt (iv) lt (iii)

C

(ii) lt (iii) lt (i) lt (iv)

D

(iii) lt (i) lt (ii) lt (iv)

Text Solution

Verified by Experts

The correct Answer is:
B

`{:([Fe(CN)_6]^(4-),"No. of unpaired electrons=0"),([Fe(CN)_6]^(3-),"No. of unpaired electrons=1"),([Ni(H_2O)_4]^(2+),"No. of unpaired electrons=2"),([Cr(NH_3)_6]^(3+),"No. of unpaired electrons=3"):}`
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Transition metals and many of their compounds show paramagnetic behaviour where there are unpaired electron or electrons. The magnetic moment arises from the spin and orbital motions in ions or molecule. Magnetic moment of n unpaired electrons is given as mu=sqrt(n(n+2)) Bohr magneton Magnetic moment increases as the number of unpaired electrons increases. Q. Increasing value of magnetic moment of (I) [Fe(CN)_6]^(4-) (II) [Fe(CN)_6]^(3-) , (III) [Cr(NH_3)_6]^(3+) (IV) [Ni(H_2O)_4]^(2+) is:

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MARVEL PUBLICATION-D AND F BLOCK ELEMENTS -TEST YOUR GRASP
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