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Pick out the incorrect statement for XeF...

Pick out the incorrect statement for `XeF_(4)`.

A

`XeF_4` disproportionate violently with water

B

It is used as fluorinating agent

C

It has octahedral structure (or geometry)

D

It oxidizes `I^(-)" to "I_2`

Text Solution

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The correct Answer is:
D

According to VSEER theory, six electrons pairs form an octahedron with two positions occupied by lone pairs. This results in square planar structure of `XeF_4`.
(a) `XeF_(4)+2SF_(4) to Xe+2SF_(6)`
`XeF_(4)` is reduced to Xe and also oxidized to `XeO_(3)`.
(b) (i) `XeF_(4)+2SF_(4) to Xe+2SF_(6)`
(ii) `3XeF_(4)+2Pt to 3Xe + 2PtF_(6)`
(iii) `XeF_(4)+C_(6)H_(6) to Xe+C_(6)H_(5)F+HF`
(d) `XeF_(4)+4KI to 4KF+Xe +2I_(2)`
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