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Identify (X), (Y) and (Z) in the given r...

Identify (X), (Y) and (Z) in the given reaction.
`CH_(3)COCH_(3) overset(I_(2)+NaOH)underset("heat") to X overset(Ag)underset("heat") to Y overset(H_(2)SO_(4)//HgSO_(4))underset("heat") to Z`

A

`X=CHI_(3), Y=CH_(3)CHO, Z=HCHO`

B

`X=CHI_(3), Y=CH_(3)OH, Z=CH_(3)CHO`

C

`X=CHI_(3), Y=CH-=CH, Z=CH_(3)CHO`

D

`X=CH_(3)COCI_(3), Y=CH_(2)=CH_(2), Z=CH_(3)CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To identify the compounds (X), (Y), and (Z) in the given reaction sequence, we will analyze each step of the reaction systematically. ### Step 1: Identify the starting compound The starting compound is acetone, which has the chemical formula \( CH_3COCH_3 \). ### Step 2: Reaction of acetone with iodine and sodium hydroxide When acetone reacts with iodine (\( I_2 \)) and sodium hydroxide (\( NaOH \)) under heating conditions, it undergoes the iodoform reaction. This reaction is characteristic of methyl ketones. The major product formed is iodoform, which has the formula \( CHI_3 \). Therefore, we can identify: - **(X) = Iodoform (\( CHI_3 \))** ### Step 3: Reaction of iodoform with silver Next, the iodoform (\( CHI_3 \)) reacts with silver metal (\( Ag \)) under heating conditions. This reaction leads to the formation of acetylene (\( C_2H_2 \)) and silver iodide (\( AgI \)). The reaction can be summarized as follows: - **(Y) = Acetylene (\( C_2H_2 \))** ### Step 4: Reaction of acetylene with sulfuric acid and mercuric sulfate Finally, acetylene (\( C_2H_2 \)) reacts with sulfuric acid (\( H_2SO_4 \)) in the presence of mercuric sulfate (\( HgSO_4 \)) under heating conditions. This reaction follows Markovnikov's rule and results in the formation of an enol, which subsequently tautomerizes to form a ketone. In this case, the product formed is acetaldehyde (\( CH_3CHO \)): - **(Z) = Acetaldehyde (\( CH_3CHO \))** ### Summary of products: - **(X) = Iodoform (\( CHI_3 \))** - **(Y) = Acetylene (\( C_2H_2 \))** - **(Z) = Acetaldehyde (\( CH_3CHO \))** ### Final Answer: - (X) = Iodoform - (Y) = Acetylene - (Z) = Acetaldehyde ---

To identify the compounds (X), (Y), and (Z) in the given reaction sequence, we will analyze each step of the reaction systematically. ### Step 1: Identify the starting compound The starting compound is acetone, which has the chemical formula \( CH_3COCH_3 \). ### Step 2: Reaction of acetone with iodine and sodium hydroxide When acetone reacts with iodine (\( I_2 \)) and sodium hydroxide (\( NaOH \)) under heating conditions, it undergoes the iodoform reaction. This reaction is characteristic of methyl ketones. The major product formed is iodoform, which has the formula \( CHI_3 \). Therefore, we can identify: - **(X) = Iodoform (\( CHI_3 \))** ...
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NCERT FINGERTIPS-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-Chemical Reactions
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  2. Which of the following reagents are not correctly matched with the rea...

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  3. Identify (X), (Y) and (Z) in the given reaction. CH(3)COCH(3) overse...

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  4. Identify (X), (Y) and (Z) retgents in the given sequence of reaction. ...

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  5. Which of the following does not answer iodoform test ?

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  6. A compound 'A' having the molecular formula C(5)H(12)O, on oxidation ...

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  7. Write a test to differentiate between pentan-2-one and pentan-3-one.

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  8. An organic compound of molecular formula C(3)H(6)O did not give a silv...

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  9. Which is the correct method of synthesising acetamide from acetone?

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  10. Compound (X) with molecular formula C(3)H(8)O is treated with acidifie...

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  11. Few simple chemical tests are given below to differentiate between the...

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  12. Which of the following will not give aldol condensation ?

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  13. The claisen schmidt condensation product of benzaldehyde and acetone i...

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  14. Study the following sequence of reaction and identify the product (Y)....

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  15. Identify (X), (Y) and (Z) in the given reaction. X +Y overset(Z) to ...

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  16. Propanal on treatment with dilute sodium hydroxide gives

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  17. Aldehydes that do not undergo aldol condensation are (1) propanal (...

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  18. The order of reactivity of CH(3)CHO, CH(3)COC(2)H(5) and CH(3)COCH(3) ...

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  19. The final product (Y) in the following sequence of chemical reaction i...

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  20. Which of the following is a correct statement ?

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