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Study the following sequence of reaction...

Study the following sequence of reaction and identify the product (Y).
`CH_(3)CHO +HCHO overset("dil."NaOH)underset("heat") to X overset(HCN) underset(H_(3)O^(+)) to Y`

A

`CH_(2)=CH-underset(OH)underset(|)(CH)-COOH`

B

`CH_(3)-overset(CN)overset(|)underset(OH)underset(|)C-COOH`

C

`CH_(3)CH_(2)-underset(OH) underset(|)CH-COOH`

D

`CH_(2)=CH-underset(CN)underset(|)(CH)-COOH`

Text Solution

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The correct Answer is:
To identify the product (Y) from the given sequence of reactions, we will analyze each step carefully. ### Step 1: Identify the Reactants The reactants are: - Acetaldehyde (CH₃CHO) - Formaldehyde (HCHO) ### Step 2: Reaction with Dilute NaOH and Heat When acetaldehyde reacts with formaldehyde in the presence of dilute NaOH and heat, an aldol condensation reaction occurs. 1. **Formation of Enolate Ion**: - Acetaldehyde has an alpha hydrogen that can be abstracted by NaOH, forming an enolate ion. - The enolate ion acts as a nucleophile. 2. **Nucleophilic Addition**: - The enolate ion attacks the carbonyl carbon of formaldehyde, leading to the formation of a β-hydroxy aldehyde (an aldol). The structure of the intermediate product (X) formed is: - **Product X**: 3-hydroxybutanal (CH₂(OH)CH₂CHO) ### Step 3: Reaction with HCN and Hydrolysis Next, product X undergoes a reaction with hydrogen cyanide (HCN) followed by hydrolysis. 1. **Nucleophilic Addition of HCN**: - The carbonyl carbon of the β-hydroxy aldehyde (X) is electrophilic and can react with HCN. - This results in the formation of a cyanohydrin. 2. **Hydrolysis**: - The cyanohydrin can be hydrolyzed to form an amide and then further hydrolyzed to yield a carboxylic acid. The final product (Y) after hydrolysis is: - **Product Y**: 3-hydroxybutanoic acid (CH₂(OH)CH₂COOH) ### Final Answer The product (Y) formed from the given sequence of reactions is **3-hydroxybutanoic acid**. ---

To identify the product (Y) from the given sequence of reactions, we will analyze each step carefully. ### Step 1: Identify the Reactants The reactants are: - Acetaldehyde (CH₃CHO) - Formaldehyde (HCHO) ### Step 2: Reaction with Dilute NaOH and Heat ...
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NCERT FINGERTIPS-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-Chemical Reactions
  1. Which of the following will not give aldol condensation ?

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  2. The claisen schmidt condensation product of benzaldehyde and acetone i...

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  3. Study the following sequence of reaction and identify the product (Y)....

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  4. Identify (X), (Y) and (Z) in the given reaction. X +Y overset(Z) to ...

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  5. Propanal on treatment with dilute sodium hydroxide gives

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  6. Aldehydes that do not undergo aldol condensation are (1) propanal (...

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  7. The order of reactivity of CH(3)CHO, CH(3)COC(2)H(5) and CH(3)COCH(3) ...

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  8. The final product (Y) in the following sequence of chemical reaction i...

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  9. Which of the following is a correct statement ?

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  10. Which of the following is the most reactive isomer ?

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  11. When propanal reacts with 2- methylpropanal in presence of NaOH, four ...

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  12. Fill in the reagents for the given conversion : CH(3)COCl overset((...

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  13. Which compound is obtained when acetaldehyde is treated with dilute s...

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  14. Which of the following compounds will undergo self aldol condensation ...

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  15. Which of the following compounds will undergo Cannizzaro reaction ?

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  16. Which of the following does not undergo Cannizzaro reaction?

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  17. Fill in the blanks by suitable choices. The carbon atom in carbonyl ...

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  18. Match the column I with column II and mark the appropriate choice .

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  19. Which of the following aldehydes will show Cannizzaro reaction ?

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  20. overset(" CHO")underset(" CHO")("|")overset(NaOH)toX The product...

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