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The electronic configurations of Cr^24 a...

The electronic configurations of `Cr^24` and `Cu^29` are abnormal -

A

Due to extra stability of exactly half filled and exactly fully filled sub shells

B

Because they belong to d-block

C

both (a) and (b)

D

None of the above

Text Solution

Verified by Experts

The correct Answer is:
A

(a) `Cr_24 - 1 s^2 2 s^2 2 p^6 3 s^2 4 s^2 3 d^4`
(original configuration)
but `- d^5 -` its's half-filled state and that is state most stable than other state.
`Cr_24 - 1 s^2 2 s^2 2 p^6 3 s^6 4 s^1 3 d^5`
As above full filled stata that is most stable than other state.
`Cu - 1 s^2 2 s^2 2 p^6 3 s^2 3 p^6 4 s^2 3 d^9`
but `1 s^2 2 s^2 2 p^6 3 s^2 3 p^6 4 s^1 3 d^10` (full filled).
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  4. The below configuration is not correct as it violates .

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  5. The maximum probability of finding electron in the d(xy) orbital is -

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  11. Which orbitals is non-directional ?

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