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A gas can be liquefied by pressure alone...

A gas can be liquefied by pressure alone when its temperature

A

higher than its critical temperature

B

lower than its critical temperature

C

either of these

D

none

Text Solution

Verified by Experts

The correct Answer is:
B

A gas cab be liquefied only if its temperature is lower than its critical temperature.
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The essential conditions for liquefaction of gases were discovered by Andrews in 1869 as a result of his study of pressure-volume-temperature relationship for CO_(2) . If was found that above a certain temperature, it was impossible to liquefy a gas whatever the pressure was applied. The temperature below which the gas can be liquefied by the application of pressure alone is called critical temperature (T_(c)) . The pressure required to liquefy a gas at this temperature is called the critical pressure (P_(c)) . The volume occupied by one mole of the substance at the critical temperature and pressure is called critcal volume. Critical constants are related with van der Waals' constant as follows: V_(c) = 3b, P_(c) = (a)/(27b^(2)), T_(c) = (8a)/(27 Rb) Gas A and can be liquefied at room temperature by applying pressure but gas B cannot. This reflects:

A2Z-STATES OF MATTER-Van Der Waals Gas Equation And Liquefaction Of Gases
  1. If bar(V) is the observed molor volume of real gas and bar(V)(id) is t...

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  2. Which of the following is the correct set of volume calculated by idea...

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  3. A gas can be liquefied by pressure alone when its temperature

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  4. Regarding the van der Waals constant which of the following is/are cor...

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  5. Which of the following satisfies the greater compressibility of real g...

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  6. The correct order of normal boiling of O(2), N(2), NH(3) and CH(4) for...

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  7. Which of the following characterstics the critical point?

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  8. A real gas most closely approaches the behaviour of an ideal gas at:

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  9. Which of the following is true at the critical point?

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  10. Which of the given sets of temperature and pressure will cause a gas t...

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  11. The ratio a/b (the terms used in van der Waals' equation) has the unit...

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  12. Which of the following is most suitable for liquefaction?

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  13. Under critical conditions, the compressibility factor for a gas is .

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  14. For which of the following gas/gases, (P(C )V(C ))/(RT(C )) close to 0...

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  15. The temperature at which a real gas obeys the ideal gas laws over a wi...

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  16. Weight of 112 ml of oxygen at NTP on liquefaction would be

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  17. Virial equation is: PV(M)=RT[A+(B)/(V(M))+(C )/(V(M^(2)))+…], where A,...

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  18. It is eaiser to liquefy oxygen than hydrogen because.

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  19. Which of the following statements is incorrect?

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  20. It is possible to liquefy a gas

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