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(1) For the given heat of reaciton, (i...

(1) For the given heat of reaciton,
(i) `C(s)+O_(2)(g)=CO_(2)(g)+97 kcal`
(ii) `CO_(2)(g)+C(s)=2CO(g)-39 kcal`
the heat of combustion of `CO(g)` is:

A

`68Kcal`

B

`-68Kcal`

C

`+48Kcal`

D

None

Text Solution

Verified by Experts

The correct Answer is:
A

Subtracting equattion (ii) from equation (i), we get
`C(s)+O_(2)(g)=CO_(2)(g)+97Kcal`
`(CO_(2)(g)+C(s)=2CO(g)-39Kcal)/(or -CO_(2)(g)+O_(2)(g)-2CO(g)+136Kcal)`
or, `2CO(g)+O_(2)=CO_(2)(g)+136Kcal`
or, `CO(g)+1//2O_(2)(g)=CO_(2)(g)68Kcal`
Required value `=68Kcal`
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