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Two moles of ideal gas at 27^(@)C temper...

Two moles of ideal gas at `27^(@)C` temperature is expanded reversibly from `2` litre to `20` liter. Find entropy change `(R=2cal//molK)`.

A

`92.1`

B

`0`

C

`4`

D

`9.2`

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The correct Answer is:
To find the entropy change (ΔS) for the reversible expansion of an ideal gas, we can use the formula: \[ \Delta S = nR \ln \left( \frac{V_f}{V_i} \right) \] Where: - \( n \) = number of moles of gas - \( R \) = universal gas constant - \( V_f \) = final volume - \( V_i \) = initial volume ### Step-by-Step Solution: **Step 1: Convert the temperature to Kelvin.** - The given temperature is \( 27^\circ C \). - To convert Celsius to Kelvin, use the formula: \[ T(K) = T(°C) + 273 \] - Thus, \[ T = 27 + 273 = 300 \, K \] **Step 2: Identify the given values.** - Number of moles, \( n = 2 \, \text{moles} \) - Initial volume, \( V_i = 2 \, \text{liters} \) - Final volume, \( V_f = 20 \, \text{liters} \) - Gas constant, \( R = 2 \, \text{cal/mol K} \) **Step 3: Substitute the values into the entropy change formula.** - We need to calculate \( \frac{V_f}{V_i} \): \[ \frac{V_f}{V_i} = \frac{20}{2} = 10 \] - Now substitute into the entropy change formula: \[ \Delta S = nR \ln \left( \frac{V_f}{V_i} \right) \] \[ \Delta S = 2 \times 2 \times \ln(10) \] **Step 4: Calculate \( \ln(10) \).** - The natural logarithm of 10 is approximately \( 2.303 \). - Thus, \[ \Delta S = 2 \times 2 \times 2.303 \] **Step 5: Perform the multiplication.** - Calculate: \[ \Delta S = 4 \times 2.303 = 9.212 \, \text{cal/K} \] ### Final Answer: The entropy change \( \Delta S \) is approximately \( 9.2 \, \text{cal/K} \).

To find the entropy change (ΔS) for the reversible expansion of an ideal gas, we can use the formula: \[ \Delta S = nR \ln \left( \frac{V_f}{V_i} \right) \] Where: - \( n \) = number of moles of gas ...
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