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For the reaction PCI(3)(g) + CI(2)(g)hAr...

For the reaction `PCI_(3)(g) + CI_(2)(g)hArrPCI_(5)(g)`, the value of `K_(p)` at `250^(@)`C is `0.61` `atm^(-1)`. The value of `K_(c)` at this temperature will be

A

15 `(mol//I)^(-1)`

B

26 `(mol//I)^(-1)`

C

35 `(mol//I)^(-1)`

D

52 `(mol//I)^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
B

`PCI_(3)(g) + CI_(2)(g)hArrPCI_(5)(g)`
`Delta n = -1, K_(p) = 0.61 atm^(-1)`
`K_(C) = K_(p)(RT)^(-Delta n)`
`= 0.61 (0.0821xx523)^(1) = 26 mol//L`
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