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15 moles of H(2) and 5.2 moles of I(2) a...

15 moles of `H_(2)` and `5.2` moles of `I_(2)` are mixed are allowed to attain equilibrium at `500^(@)C`. At equilibrium the concentration of HI is found to be 10 moles. The equilibrium constant for the formation of HI is

A

50

B

15

C

100

D

25

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The correct Answer is:
To find the equilibrium constant \( K_c \) for the reaction between hydrogen and iodine to form hydrogen iodide, we can follow these steps: ### Step 1: Write the Balanced Chemical Equation The reaction can be represented as: \[ H_2(g) + I_2(g) \rightleftharpoons 2 HI(g) \] ### Step 2: Identify Initial Moles From the problem, we have: - Initial moles of \( H_2 = 15 \) moles - Initial moles of \( I_2 = 5.2 \) moles - At equilibrium, the moles of \( HI = 10 \) moles ### Step 3: Determine Change in Moles Let \( x \) be the amount of \( H_2 \) that reacts. Since the stoichiometry of the reaction shows that 1 mole of \( H_2 \) reacts with 1 mole of \( I_2 \) to produce 2 moles of \( HI \), we can express the changes in moles as follows: - Moles of \( H_2 \) at equilibrium: \( 15 - x \) - Moles of \( I_2 \) at equilibrium: \( 5.2 - x \) - Moles of \( HI \) at equilibrium: \( 2x \) Given that at equilibrium \( 2x = 10 \), we can solve for \( x \): \[ x = \frac{10}{2} = 5 \] ### Step 4: Calculate Moles at Equilibrium Now we can substitute \( x \) back to find the equilibrium moles: - Moles of \( H_2 \) at equilibrium: \[ 15 - 5 = 10 \text{ moles} \] - Moles of \( I_2 \) at equilibrium: \[ 5.2 - 5 = 0.2 \text{ moles} \] ### Step 5: Write the Expression for \( K_c \) The equilibrium constant \( K_c \) is given by the expression: \[ K_c = \frac{[HI]^2}{[H_2][I_2]} \] Where \( [C] \) denotes the concentration of species \( C \). ### Step 6: Calculate Concentrations Assuming the volume of the reaction vessel is \( V \): - Concentration of \( HI \): \[ [HI] = \frac{10}{V} \] - Concentration of \( H_2 \): \[ [H_2] = \frac{10}{V} \] - Concentration of \( I_2 \): \[ [I_2] = \frac{0.2}{V} \] ### Step 7: Substitute Values into \( K_c \) Expression Now substituting the concentrations into the \( K_c \) expression: \[ K_c = \frac{\left(\frac{10}{V}\right)^2}{\left(\frac{10}{V}\right)\left(\frac{0.2}{V}\right)} \] ### Step 8: Simplify the Expression The \( V \) cancels out: \[ K_c = \frac{100}{10 \times 0.2} = \frac{100}{2} = 50 \] ### Final Answer Thus, the equilibrium constant \( K_c \) for the formation of \( HI \) is: \[ \boxed{50} \]

To find the equilibrium constant \( K_c \) for the reaction between hydrogen and iodine to form hydrogen iodide, we can follow these steps: ### Step 1: Write the Balanced Chemical Equation The reaction can be represented as: \[ H_2(g) + I_2(g) \rightleftharpoons 2 HI(g) \] ...
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