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Assertion: The dissociation of PC1(5) de...

Assertion: The dissociation of `PC1_(5)` decreases on increase.
Reason: An increase in pressure favours the forward reaction.

A

If both assertion and reason are true and the reason is the correct explanation of the assertion.

B

If both assertion and reason are true but reason is not the correct explanation of the assertion.

C

If assertion is true but reason is false.

D

If assertion is false but reason is true.

Text Solution

Verified by Experts

The correct Answer is:
C

`{:(PCl_(5),hArr,PCl_(3),+,Cl_(2)),(1,,0,,0),(1-alpha,,alpha,,alpha):}`
`K_(p) = [(alpha^(2))/(1-alpha)] [(P)/(1+alpha)]^(1)`
An increase in pressure will decrease `alpha`, to have `K_(p)` constant and thus backward reaction occurs.
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