Home
Class 11
CHEMISTRY
Assertion: The dissociation of PC1(5) de...

Assertion: The dissociation of `PC1_(5)` decreases on increasing pressure.
Reason: An increase in pressure favours the forward reaction.

A

If both assertion and reason are true and the reason is the true explanation of the assertion.

B

If both the assertion and reason are true but the reason is not the correst explanation of assertion.

C

If the assertion is true but reason is false.

D

If assertion is false but reason is true.

Text Solution

Verified by Experts

The correct Answer is:
C

`{:(PCl_(5),hArr,PCl_(3),+,Cl_(2)),(1,,0,,0),(1-alpha,,alpha,,alpha):}`
`K_(p) = [(alpha^(2))/(1 - alpha)][(P)/(1 + alpha)]^(1)`
An increase in pressure will decrease `alpha` , to have `K_(p)` constant and thus backward reaction occurs.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • CHEMICAL EQUILIBRIUM

    A2Z|Exercise AIIMS Questions|27 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • CHEMICAL THERMODYNAMICS

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Assertion: The dissociation of PC1_(5) decreases on increase. Reason: An increase in pressure favours the forward reaction.

The degree of dissociation of PCl_(5) decreases with increase in pressure.

The reaction in which an increase in pressure would favour the forward reaction is

Assertion: The melting point of solid (except ice) increases with increase in pressure. Reason: An increasion in pressure favours the change where volume decreases.

The melting of ice in water decreases with increase in pressure.

Assertion: The solubility of gases always increases with increase in pressure. Reason: High pressure favours the change where volume decreases.

For which of the following equilibria does decrease in pressure not favour the forward reaction ?

Assertion : The melting point of ice decreases with increase of pressure Reason : Ice contract on melting.