Home
Class 11
CHEMISTRY
In a reaction at equilibrium, 'x' mole o...

In a reaction at equilibrium, `'x'` mole of reactant `A` decompose to give `1 molar` of `C` and `D`. It has been found that the fraction of `A` decomposed at equilibrium is independent of initial concentration of `A`. Find the value of `x`.

A

1

B

3

C

2

D

4

Text Solution

Verified by Experts

The correct Answer is:
C

`{:(xA,,hArr,,C,+,D,),(a,,,,0,,0,"at intial"),(a(1-a),,,,(aalpha)/x,,(aalpha)/x,"at equilibrium"):}`
`K = ([C][D])/([A]^(x)) = (((alpha^(2)a^(2))/x^(2)v^(2)))/([(a(1-alpha))/(V)]^(x))`
`= (alpha^(2)a^(2-alpha))/(x^(2)(1-alpha)^(x)V^(2-x))`
`.: alpha` is independent of A `implies 2 - x =0` or x = 2
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    A2Z|Exercise Assertion - Reasoning Questions|5 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • CHEMICAL THERMODYNAMICS

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

In a reaction at equilibrium, 'x' mole of reactant A decompose to give 1 molar of C and D . It has been found that the fraction of A decomposed at equilibrium is independent of initial concentration of A . Calculate x .

In a gaseous reaction at equilibrium , 'n' mole of reactant 'A' decompose to give 1 mole each of C and D.It has been found that degree of dissociation of A at equilibrium is independent of total pressure.Value of 'n' is :

Assertion : The equilibrium constant for the reverse reaction is equal to the inverse of the equilibrium constant for the forward reaction . Reason : The value of equilibrium constant is independent of initial concentrations of the reactants and products.

Influence of pressure, temperature, concentration and addition of inert gas on a reversible chemical reaction in equilibrium can be explained by formulating the expression for equilibrium constant K_(c) or K_(p) for the equilibrium. On the other hand Le Chatelier principle can be theoretically used to explain the effect of P , T or concentration on the physical or chemical equilibrium both. n moles of a reactant A gives one mole of B and C . If degree of dissociation of A is independent of initial concentration of A , then n is:

If the half-time for a particular reaction is found to be constant and independent of the initial concentration of the reactants, then the reaction is of

In the reaction A+B hArr C+D , What will happen to the equilibrium if concentration of A is increased ?

At a definite temperature, the equilibrium constant for a reaction, A+BhArr2C , was found to be 81. Starting with 1 mole A and 1 mole B, the mole fraction of C at equilibrium is :

For the reaction 3AhArr C+2D , initially A was taken. At equilibrium the concentration of D is twice that of A. The value of K_(c) is

A2Z-CHEMICAL EQUILIBRIUM-Section D - Chapter End Test
  1. If pressure is applied to the following equilibrium, liquid hArr vapou...

    Text Solution

    |

  2. For the reaction, A+BhArr3C, at 25^(@)C, a 3 litre vessel contains 1, ...

    Text Solution

    |

  3. The equilibrium constant for a reacton N(2)(g)+O(2)(g)=2NO(g) is 4xx...

    Text Solution

    |

  4. In the system A((s))hArr2B((g))+3C((g)), if the concentration of C at ...

    Text Solution

    |

  5. In a reaction at equilibrium, 'x' mole of reactant A decompose to give...

    Text Solution

    |

  6. If CuSO(4).5H(2)O((s))hArrCuSO(4).3H(2)O((s)) + 2H(2)O((l)) K(p) = 1.0...

    Text Solution

    |

  7. In the system, LaCI(3(s)) + H(2)O(g) + heat rarr LaCIO(s) + 2HCI(g) , ...

    Text Solution

    |

  8. The equilibrium constant for the reaction N(2)(g)+O(2)(g) hArr 2NO(g) ...

    Text Solution

    |

  9. For the decomposition reaction: NH(2)COONH(4(s))hArr2NH(3(g))+CO(2(g...

    Text Solution

    |

  10. For a reaction A((g)) + B((g))hArrC((g)) + D((g)) the intial concentra...

    Text Solution

    |

  11. The partial pressure of CH(3)OH((g)), CO((g)) and H(2(g)) in equilibri...

    Text Solution

    |

  12. For reaction A(g) + B(g) we start with 2 moles of A and B each. At equ...

    Text Solution

    |

  13. In the reversible reaction A + B hArr C + D, the concentration of each...

    Text Solution

    |

  14. 2 moles of PCl(5) was heated in a closed vessel of 2 litre capacity. A...

    Text Solution

    |

  15. A mixture of 0.3 mole of H(2) and 0.3 mole of I(2) is allowed to react...

    Text Solution

    |

  16. CH(3)COOH((l)) + C(2)H(5)OH((l))hArrCH(3)COOC(2)H(5(l)) + H(2)O((l)) I...

    Text Solution

    |

  17. If the equilibrium constant of the reaction 2HI hArrH(2) + I(2) is 0.2...

    Text Solution

    |

  18. Assertion : K(p) = K(c) for all reaction. Reason : At constant tempe...

    Text Solution

    |

  19. Assertion : The equilibrium constant for the reaction CaSO(4).5H(2)O(s...

    Text Solution

    |

  20. Assertion : On cooling a freezing mixture, color of the mixture turns ...

    Text Solution

    |