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The dissocication constant of a weak aci...

The dissocication constant of a weak acid is `1.0xx10^(-5)`, the equilibrium constant for the reaction with strong base is

A

`1.0xx10^(-5)`

B

`1.0xx10^(-9)`

C

`1.0xx10^(9)`

D

`1.0xx10^(14)`

Text Solution

Verified by Experts

The correct Answer is:
C

`HAhArrH^(+)+A^(-)` , `K_(a)=([H^(+)][A^(-)])/([HA])` (`i`)
neutralization of the weak acid with strong base is
`HA+OH^(-)hArrA^(-)+H_(2)O`
`K=([A^(-)])/([HA][OH^(-)])` (`ii`)
Dividing (`i`) by (`ii`), `(K_(a))/(K)=[H^(+)][OH^(-)]=K_(w)=10^(-14)`
`K=(K_(a))/(K_(w))=(10^(-5))/(10^(-14))=10^(9)`
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