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By adding 20 ml 0.1 N HCl to 20 ml 0.001...

By adding `20 ml 0.1 N HCl` to `20 ml 0.001 N KOH`, the `pH` of the obtained solution will be

A

`2`

B

`1.3`

C

`0`

D

`7`

Text Solution

Verified by Experts

The correct Answer is:
B

`20ml` of `0.1 NHCl=(0.1)/(1000)xx20g eq=2xx10^(-3)g eq.`
`20 ml` of `0.001 KOH=(0.001)/(1000)xx20g eq`
`=2xx10^(-5) g eq.`
`:. HCl` left unneutralised `=2(10^(-3)-10^(-5))`
`= 2xx10^(-3)(1-0.01)=2xx0.99xx10^(-3)=1.98xx10^(-3)g eq.`
Volume of solution `=40 ml`
`:. [HCl]=(1.98xx10^(-3))/(40)xx1000M=4.95xx10^(-2)`
`:. pH=2-log 4.95=2-0.7=1.3`
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