Home
Class 11
CHEMISTRY
Assertion: The ionic radii follows the o...

Assertion: The ionic radii follows the order: `I^(-) lt I lt I^(+)`.
Reason: The smaller the value of `Z//e` the larger the size of the species.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If the assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If assertion is false but reason is true.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that the ionic radii follows the order: \( I^- < I < I^+ \). This means that the radius of the iodide ion (\( I^- \)) is smaller than that of neutral iodine (\( I \)), which is smaller than that of the iodide cation (\( I^+ \)). 1. **Understanding Ionic Radii**: - Anions (negatively charged ions) are generally larger than their neutral atoms because they have gained electrons, which increases electron-electron repulsion. - Cations (positively charged ions) are generally smaller than their neutral atoms because they have lost electrons, which decreases electron-electron repulsion and allows the remaining electrons to be pulled closer to the nucleus. 2. **Conclusion for Assertion**: - The correct order of ionic radii should actually be \( I^- > I > I^+ \). Therefore, the assertion \( I^- < I < I^+ \) is incorrect. ### Step 2: Analyze the Reason The reason states: "The smaller the value of \( Z/e \), the larger the size of the species." Here, \( Z \) represents the charge of the nucleus and \( e \) represents the charge of the electron. 1. **Understanding \( Z/e \)**: - The ratio \( Z/e \) indicates the effective nuclear charge experienced by the electrons. A smaller \( Z/e \) value suggests that the electrons are less tightly held by the nucleus, leading to a larger ionic radius. - In the context of ions, anions have a larger size due to the increased electron-electron repulsion, while cations have a smaller size due to the reduced electron-electron repulsion. 2. **Conclusion for Reason**: - The statement about \( Z/e \) is correct. A smaller \( Z/e \) indeed corresponds to a larger ionic size. ### Final Conclusion - The assertion is incorrect, while the reason is correct. However, since the assertion is incorrect, the reason cannot be used to justify the assertion. ### Summary of the Solution - Assertion: \( I^- < I < I^+ \) is incorrect; the correct order is \( I^- > I > I^+ \). - Reason: The statement about \( Z/e \) is correct. - Therefore, the assertion is false, and the reason is true, but the reason does not support the assertion.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that the ionic radii follows the order: \( I^- < I < I^+ \). This means that the radius of the iodide ion (\( I^- \)) is smaller than that of neutral iodine (\( I \)), which is smaller than that of the iodide cation (\( I^+ \)). 1. **Understanding Ionic Radii**: - Anions (negatively charged ions) are generally larger than their neutral atoms because they have gained electrons, which increases electron-electron repulsion. - Cations (positively charged ions) are generally smaller than their neutral atoms because they have lost electrons, which decreases electron-electron repulsion and allows the remaining electrons to be pulled closer to the nucleus. ...
Promotional Banner

Topper's Solved these Questions

  • CLASSIFICATION OF ELEMENTS AND PERIODICITY OF PROPERTIES

    A2Z|Exercise AIPMT/ NEET Questions|13 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY OF PROPERTIES

    A2Z|Exercise AIIMS Questions|24 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY OF PROPERTIES

    A2Z|Exercise Electronegativity And Nature Of Oxides|42 Videos
  • CHEMICAL THERMODYNAMICS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • CLASSIFICTION, PURIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Assertion : The order of atomic radii of Cu, Ag and Au is Cu lt Ag ~~ Au . Reason : The atomic radii of 4d series elements are larger than those of 3d series elements but generally the radii of 4d and 5d series elements are almost identical.

Assertion: Order of lattice energy for same halides are as LiX lt NaX lt KX . Reason: Size of alkaline -earth metal increases from Li to K

Assertion (A): The ionic size of Mg^(2+) is larger than Al^(3+) Assertion (R): In isoelecronic species, greater the nuclear charge, less is the size

Assertion : Susceptibility is defined as the ratio of intensity of magnetisation I to magnetic intensity H. Reason : Greater the value of susceptibility, smaller the value of intensity of magnetisation I.

In AgBr crystal , the ion size lies in the order Ag^(+) lt lt Br^(-) The AgHt crystal should have the following characheristics

A2Z-CLASSIFICATION OF ELEMENTS AND PERIODICITY OF PROPERTIES-Section B - Assertion Reasoning
  1. Assertion: the decreasing order of acidic character of CO(2),N(2)O(5),...

    Text Solution

    |

  2. Assertion: NO is an acidic oxide while CrO(3) is a basic oxide. Reas...

    Text Solution

    |

  3. Assertion: F is more electronegative than Cl. Reason: F has high ele...

    Text Solution

    |

  4. Assertion: E^(@) for Mn^(3+)//Mn^(2+) is more positive than Cr^(3+)//C...

    Text Solution

    |

  5. Assertion: The ionic size of O^(2-) is bigger than that of F^(-) ions....

    Text Solution

    |

  6. Assertion: The ionic radii follows the order: I^(-) lt I lt I^(+). R...

    Text Solution

    |

  7. Assertion: Sixth period is the longest period in the periodic table. ...

    Text Solution

    |

  8. Assertion: Electron gain enthalpy always becomes less negative as we g...

    Text Solution

    |

  9. Assertion: Electron gain enthalpy value of the 3rd peirod p-block elem...

    Text Solution

    |

  10. Assertion: Of the elements , helium has the highest value of first ion...

    Text Solution

    |

  11. Assertion: The first ionisation enthalpy of aluminium is lower than th...

    Text Solution

    |

  12. Assertion: Helium and beryllium have similar outer electronic configur...

    Text Solution

    |

  13. Assertion: the 4f^(-) and 5f^(-) inner transition series of elements a...

    Text Solution

    |

  14. Assertion: The atomic radii of the elements of the oxygen family are s...

    Text Solution

    |

  15. Assertion: F atom has less negative electron gain enthaply than Ci ato...

    Text Solution

    |

  16. Assertion: The first ionisation energy of Be is greater than that of B...

    Text Solution

    |

  17. Assertion: In general, for an element, IE(1) lt IE(2) lt IE(3).... R...

    Text Solution

    |

  18. Assertion: Generally, ionisation enthalpy than beryllium. Reason: Wh...

    Text Solution

    |

  19. Assertion: Boron has a smaller first ionisation enthalpy than berylliu...

    Text Solution

    |

  20. Assertion: Metallic character of first group metals of Modern periodic...

    Text Solution

    |