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Assertion: In general, for an element, I...

Assertion: In general, for an element, `IE_(1) lt IE_(2) lt IE_(3)....`
Reason: After the removal of each successive electron remaining electrons are held more tightly by the nucleus so removal of next electron becomes difficult.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If the assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If assertion is false but reason is true.

Text Solution

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The correct Answer is:
A
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The second ionisation energies are higher than the first ionisation energies. This is mainly due to the fact that after the removal of the first electrons, the atom changes inot mono valent position ion. In the ion, the number of electrons decreases but the nuclear charge remains the same. As a result of this, the remaining electrons are held more tightly by the nucleus and it becomes difficult to remove the second electron . Therefore, the value of second ionisation energy . (IE_(2)) , is greater than that of the first ionisation energy (IE_(1)) . Similarly third ionisation energy (IE_(3)) is greater than that of second IE_(2) . Successive ionisation energy of an atom is greater than previous one, because

The second ionisation energies are higher than the first ionisation energies. This is mainly due to the fact that after the removal of the first electrons, the atom changes inot mono valent position ion. In the ion, the number of electrons decreases but the nuclear charge remains the same. As a result of this, the remaining electrons are held more tightly by the nucleus and it becomes difficult to remove the second electron . Therefore, the value of second ionisation energy . (IE_(2)) , is greater than that of the first ionisation energy (IE_(1)) . Similarly third ionisation energy (IE_(3)) is greater than that of second IE_(2) . Correct order of ionisation potential of coinage metals is :

The second ionisation energies are higher than the first ionisation energies. This is mainly due to the fact that after the removal of the first electrons, the atom changes inot mono valent position ion. In the ion, the number of electrons decreases but the nuclear charge remains the same. As a result of this, the remaining electrons are held more tightly by the nucleus and it becomes difficult to remove the second electron . Therefore, the value of second ionisation energy . (IE_(2)) , is greater than that of the first ionisation energy (IE_(1)) . Similarly third ionisation energy (IE_(3)) is greater than that of second IE_(2) . IE_(1) and IE_(2) of Mg metal are 178 and 348 kcal/mol respectively . The energy required for the given reaction is : Mg(g)rarr Mg^(+2)(G)+2e^(-)

The second ionisation energies are higher than the first ionisation energies. This is mainly due to the fact the after the removal of the first electron, the atom changes into monovalent positive ion. In the ion, the number of electrons decreases but the nuclear charge remains the same. as a result of this, the remaining electrons are held more tightly by the nucleus and it becomes difficult to remove the second electron. therefore, the value of second ionisation energy. (IE_(2)) , is greater than that of the first ionisatio energy (IE_(1)) . similarly third ionisation energy (IE_(3)) is greater than that of second IE_(2) . Q. IE_(1) and IE_(2) of Mg metal are 178 and 348 kcal/mol respectively. the energy required for the given reaction is: Mg(s) to Mg^(+2)+2e^(-)

Statement-I : IE_(3) of Mn is more than IE_(3) of Fe. Statement-II : After the removal of 2 electron Fe acquire half filled electronic configuration.

Assertion: Boron has a smaller first ionisation enthalpy than beryllium. Reason: The penetration of a 2s electron to the nucleus is more than the 2p electron, hence 2p electorn is more shielded by the inner core of electrons than the 2s electrons.

B has a smaller first ionization enthalpy than Be. Consider the following statements (i) it is easier to remove 2p electron than 2s electron (ii) 2p electron of B is more shielded from the nucleus by the inner core of electrons than the 2s electrons of Be (iii) 2s electron has more penetration power than 2p electron (iv) atomic radius of B is more than Be (atomic number B= 5, Be = 4) The correct statements are

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