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Which of the following orders of ionic r...

Which of the following orders of ionic radii is correctly represented?

A

`H^(-) gt H^(+) gt H`

B

`Na^(+) gt F^(-) gt O^(2-)`

C

`F^(-) gt O^(2-) gt Na^(+)`

D

`Al^(3+) gt Mg^(2+) gt N^(3-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of ionic radii among the given options, we need to analyze the ionic forms of hydrogen, sodium, fluoride, oxide, aluminum, magnesium, and nitrogen. Here's a step-by-step solution: ### Step 1: Understand Ionic Forms - **Hydrogen (H)** has one proton and one electron. - **Hydride ion (H⁻)** is formed when hydrogen gains an electron, resulting in one proton and two electrons. - **Hydrogen ion (H⁺)** is formed when hydrogen loses its electron, resulting in one proton and no electrons. ### Step 2: Compare Sizes of Hydrogen Ions - **H⁻ (Hydride)**: Has two electrons, which means the effective nuclear charge (the ability of the nucleus to attract electrons) is weaker because one proton is binding two electrons. Hence, H⁻ is larger than H. - **H (Neutral Hydrogen)**: Has one proton and one electron, so it has a normal size. - **H⁺ (Hydrogen Ion)**: Has one proton and no electrons, making it the smallest since there are no electrons to repel each other. ### Step 3: Analyze Sodium, Fluoride, and Oxide Ions - **Sodium ion (Na⁺)**: Atomic number 11, loses one electron, resulting in 10 electrons. - **Fluoride ion (F⁻)**: Atomic number 9, gains one electron, resulting in 10 electrons. - **Oxide ion (O²⁻)**: Atomic number 8, gains two electrons, resulting in 10 electrons. ### Step 4: Determine Ionic Sizes - All three ions (Na⁺, F⁻, O²⁻) are isoelectronic (same number of electrons). The size of isoelectronic species depends on the number of protons: - **Na⁺ (11 protons)**: Smallest size due to the highest positive charge attracting electrons. - **F⁻ (9 protons)**: Larger than Na⁺. - **O²⁻ (8 protons)**: Largest size because it has the least positive charge. ### Step 5: Analyze Aluminum, Magnesium, and Nitrogen Ions - **Aluminum ion (Al³⁺)**: Atomic number 13, loses three electrons, resulting in 10 electrons. - **Magnesium ion (Mg²⁺)**: Atomic number 12, loses two electrons, resulting in 10 electrons. - **Nitride ion (N³⁻)**: Atomic number 7, gains three electrons, resulting in 10 electrons. ### Step 6: Determine Sizes of These Ions - All three ions are also isoelectronic. The sizes will depend on the number of protons: - **Al³⁺ (13 protons)**: Smallest size. - **Mg²⁺ (12 protons)**: Larger than Al³⁺. - **N³⁻ (7 protons)**: Largest size. ### Conclusion Based on the analysis: - The order of ionic radii from smallest to largest is: - H⁺ < Na⁺ < F⁻ < O²⁻ < Al³⁺ < Mg²⁺ < N³⁻ Since the options provided in the question are incorrect, the final answer is **None of these**.

To determine the correct order of ionic radii among the given options, we need to analyze the ionic forms of hydrogen, sodium, fluoride, oxide, aluminum, magnesium, and nitrogen. Here's a step-by-step solution: ### Step 1: Understand Ionic Forms - **Hydrogen (H)** has one proton and one electron. - **Hydride ion (H⁻)** is formed when hydrogen gains an electron, resulting in one proton and two electrons. - **Hydrogen ion (H⁺)** is formed when hydrogen loses its electron, resulting in one proton and no electrons. ### Step 2: Compare Sizes of Hydrogen Ions ...
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