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The formation of the oixde ion, O^(2+)(g...

The formation of the oixde ion, `O^(2+)(g)` from oxygen atom requires first an exothermic and then an endothermic step as shown below:
`O(g)+e^(-) rarr O^(-)(g), Delta H^(O)=-141kJ mol^(-)`
`O(g)+e^(-) rarr O^(-)(g), H^(O)=-kJ mol^(-)`
Thus the process of formation of `O^(2-)` in gas phase is neon. It is due to the fact that

A

Oxygen is more electronegative

B

addition of electrons in oxygen result in larger size of the ion

C

Electron repulsion outweighs the stability gained by achieving noble gas configuration

D

`O^(-)` ion has comparatively smaller size than oxygen atom

Text Solution

Verified by Experts

The correct Answer is:
C

Second electron gain enthalpy is positive (energy absorbed) due to more repulsion experienced by incoming electrons while entering uninegative anion.
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The formation of oxide ion O^(2-)(g) from oxygen atom requires first an exothermic and then an endothermic step as shown below O(g)+e^(-) rarr O^(-)(g), DeltaH^(-) = - 141 kj mol^(-1) O^(-)(g) +e^(-) rarr O^(2-) (g), DeltaH^(-) =+ 780 kj mol^(-1) Thus, process of formation of O^(2-) in gas phase is unfavourable even through O^(2-) is isoelectronic with neon. It is due to the fact that