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Which of the following has the minimum h...

Which of the following has the minimum heat of dissociation?

A

`[(CH_(3))_(3)NtoBF_(3)]`

B

`[(CH_(3))_(3)NtoB(CH_(3))F_(2)]`

C

`[(CH_(3))_(3)NtoB(CH_(3))_(2)F]`

D

`[(CH_(3))_(3)NtoBF_(3)]`

Text Solution

Verified by Experts

The correct Answer is:
D

The tendency of trimethyl boron to act as Lewis acid decreases due to `+IE` of `CH_(3)` group and thus, coordination becomes weaker.
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Knowledge Check

  • Which of the following has the minimum mass?

    A
    `6.02xx10^(22)H_(2)` molecules
    B
    `1120 c c` of `CO_(2)` at `STP`
    C
    `0.1` mol of `NH_(3)`
    D
    `0.1g` atom of carbon
  • Which of the following has the minimum pH ?

    A
    Blood
    B
    Gastric juice
    C
    Saliva
    D
    Milk
  • Which of the following has minimum pH?

    A
    Bile
    B
    Gastric juice
    C
    Saliva
    D
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  • A2Z-P BLOCK ELEMENTS ( Group 13 -14)-Section D - Chapter End Test
    1. Which of the following has the minimum heat of dissociation?

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    2. Electrolytic reduction of alumina to aluminium by Hall-Heroult process...

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    3. Aluminium metal is purified by :

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    4. The major role of flourspar, CaF(2) which is added in small amount in ...

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    5. In Goldschmidt reaction, certain metallic oxides are reduced to the me...

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    6. In the electrolysis of alumina, cryolite is added to

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    7. Specify the coordinate geometry around and hyridilization present abou...

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    8. The geometry and the hybirdisation present about the central atom in B...

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    9. Which of the following statements is correct?

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    10. H(3)BO(3) is.

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    11. How can the following reaction be made to proceed in forward direction...

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    12. Which halide is stable and has doubtful existence?

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    13. The correct order of decreasing C-O bond length of (1) CO,(II)CO(3)^(2...

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    14. Which is neutral to litmus?

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    15. (Me)(2) SiCl(2) on hydrolysis will produce.

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    16. Pb and sSn are exerted from their chief ores by:

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    17. PbO(2)on rection with HNO(3) gives gas:

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    18. An aqueous solution of a substance gives a white percipitate on treatm...

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    19. The name of the structure of silicates in which three oxygen atoms of ...

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    20. Which one of the following orders presents the correct sequence of the...

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