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Assign number 1 for least to 4 for most ...

Assign number `1` for least to `4` for most to indicate the relative base strength of the following
`{:(I,,II),(C_(6)H_(5)NH_(2),,p-NO_(2)C_(6)H_(4)NH_(2)),(III,,IV),(m-NO_(2)C_(6)H_(4)NH_(2),,p-CH_(3)OC_(6)H_(4)NH_(2)):}`

A

`{:(I,II,III,IV),(3,1,2,4):}`

B

`{:(I,II,III,IV),(1,2,3,4):}`

C

`{:(I,II,III,IV),(2,3,4,1):}`

D

`{:(I,II,III,IV),(4,1,3,2):}`

Text Solution

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The correct Answer is:
A

`EWG` decreases basic strength `EDG` increase basic strength
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Arrange the following anilies in decreasing order of basicity 1. C_(6)H_(5)NH_(2) o-CH_(3C_(6)H_(4)NH_(2) 3. m-CH_(3)C_(6)H_(4)NH_(2) 4. p-CH_(3)C_(6)H_(4)NH_(2)

The number of amines having pK_(b) less than C_(6)H_(5)NH_(2) among the following is P-CH_(3) C_(6)H_(5)NH_(2), o-CH_(3)C_(6)H_(4)NH_(2), m-CH_(3)C_(6)H_(4)NH_(2), C_(6)H_(5)N (CH_(3)) _(2), C_(6)H_(5)NHCH_(3), p-NO_(2)C_(6)H_(4)NH_(2), p-CIC_(6)H_(4)NH_(2), C_(6)H_(5)CH_(2)NH_(2)

Rearrange the following in an increasing order of their basic strenghts : C_(6)H_(5)NH_(2),C_(6)H_(5)N(CH_(3))_(2),(C_(6)H_(5))_(2)NH and CH_(3) NH_(2)

Write chemical equations for the following conversions: (i) CH_(3)-CH_(2)-Cl"into" CH_(3)-CH_(2)CH_(2)-NH_(2) (ii)C_(6)H_(5)-CH_(2)-Cl"into" C_(6)H_(5)-CH_(2)-NH_(2)

A2Z-SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY-Section D - Chapter End Test
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  2. Arrange the following comounds in increasing order of length of their ...

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  3. The order of heat of hydrogenation in following compounds is:

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  4. S(N)1 reaction is faster in

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  5. Which compound would be least soluble in water?

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  6. Among the following compound which can be dehydrated very easily is :

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  7. Which of the follwing is not the characteristic of the mechanism of fr...

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  8. Find the strongest acid among the following compound

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  9. Among the following the dissociation constant is highest

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  10. Which one of the following compounds is most acidic

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  11. The optically active tartaric acid is named as D-(+)- tartaric acid be...

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  12. Among the following compounds (I-II) the correct order of reaction wit...

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  13. The following reaction is described as

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  14. Which of the following is the most stable cation?

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  15. The observed dipole moment of nitromethane is highly than the dipole m...

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  16. Dehydrohalogenation in presence of OH^(-) is correct represented by

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  17. Among the following the aromatic compound is

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  18. Which of the following compounds are not arranged in order of decreasi...

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  19. Most stable carbonium ion is :

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  20. Which one of the following species is most stable

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  21. Which of the following gives most stable carbocation by dehydration

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