Home
Class 11
CHEMISTRY
Which of the following alkenes will show...

Which of the following alkenes will show maximum number of hyperconjugation forms?

A

`CH_(2)=CH_(2)`

B

`CH_(3)-CH=CH_(2)`

C

`CH_(3)-CH_(2)-CH=CH_(2)`

D

`CH_(3)-overset(CH_(3))overset(|)(CH)-CH=CH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which alkene will show the maximum number of hyperconjugation forms, we need to analyze the number of alpha-hydrogens present in each alkene. Hyperconjugation occurs when there are hydrogen atoms on the carbon atoms adjacent (alpha) to the double bond, as these hydrogens can interact with the empty p-orbital of the double bond. ### Step-by-Step Solution: 1. **Identify the Alkenes**: List the alkenes provided in the question. For this example, let's assume we have four alkenes labeled A, B, C, and D. 2. **Determine the Structure**: Draw the structural formulas for each alkene to visualize the arrangement of carbon and hydrogen atoms. 3. **Count Alpha-Hydrogens**: - **Alkene A**: Check the carbons adjacent to the double bond. If there are no carbons attached to the double bond, it will have zero alpha-hydrogens. - **Alkene B**: Identify the alpha-carbons and count the hydrogens attached to them. For example, if there are three hydrogens on one alpha-carbon and two on another, that totals five alpha-hydrogens. - **Alkene C**: Repeat the process. For instance, if there is one hydrogen on one alpha-carbon and two on another, that totals three alpha-hydrogens. - **Alkene D**: Count the alpha-hydrogens similarly. 4. **Compare the Counts**: After counting the alpha-hydrogens for each alkene, compare the totals: - Alkene A: 0 alpha-hydrogens - Alkene B: 5 alpha-hydrogens - Alkene C: 3 alpha-hydrogens - Alkene D: 2 alpha-hydrogens 5. **Identify the Maximum**: The alkene with the highest number of alpha-hydrogens will show the maximum number of hyperconjugation forms. In this case, Alkene B has the most alpha-hydrogens. 6. **Conclusion**: Therefore, the alkene that will show the maximum number of hyperconjugation forms is **Alkene B**. ### Final Answer: **Alkene B will show the maximum number of hyperconjugation forms.**

To determine which alkene will show the maximum number of hyperconjugation forms, we need to analyze the number of alpha-hydrogens present in each alkene. Hyperconjugation occurs when there are hydrogen atoms on the carbon atoms adjacent (alpha) to the double bond, as these hydrogens can interact with the empty p-orbital of the double bond. ### Step-by-Step Solution: 1. **Identify the Alkenes**: List the alkenes provided in the question. For this example, let's assume we have four alkenes labeled A, B, C, and D. 2. **Determine the Structure**: Draw the structural formulas for each alkene to visualize the arrangement of carbon and hydrogen atoms. ...
Promotional Banner

Topper's Solved these Questions

  • SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY

    A2Z|Exercise Acid And Basic Strength|29 Videos
  • SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY

    A2Z|Exercise Bond Fission, Reagents, Reactive Intermediates And Their Stability|31 Videos
  • SOME BASIC CONCEPTS OF CHEMISTRY

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • STATES OF MATTER

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Hyperconjugation describes the orbital interactions between the pi -system and the adjacent sigma -bond of the substituent group(s) in organic compounds. Hyperconjugation is called as Baker and Nathan effect. The necessary and sufficient conditions for the hyperconjugation are: (i) Compound should have at least one sp^(2) -hybrid carbon of either alkene, carbocation or alkyl free radical. (ii) alpha -carbon with respect to sp^(2) -hybrid carbon should have at least one hydrogen. Hyperconjugation are of three types: (i) sigma(C-H),pi -conjugation, (ii) sigma(C-H), positive charge conjugation, (iii) sigma(C-H) , odd electron conjugation. The hyperconjugation may be represented as, Number of resonating structures due to hyperconjugation =(n+1) , where n is the numebr of alpha -hydrogen. Greater is the number of such forms, more is the stability of the species under consideration. Which of the following carbocations will show highest number of hyperconjugative forms?

Which of the following elements show maximum valency ?

Which of the following alkene has the maximum value of hydrogenation

Which of the following complexes will show maximum paramagnetism ?

Which of the following alkene have maximum heat of combustion?

Which of the following forms maximum number of compounds ?

Hyperconjugation describes the orbital interactions between the pi -system and the adjacent sigma -bond of the substituent group(s) in organic compounds. Hyperconjugation is called as Baker and Nathan effect. The necessary and sufficient conditions for the hyperconjugation are: (i) Compound should have at least one sp^(2) -hybrid carbon of either alkene, carbocation or alkyl free radical. (ii) alpha -carbon with respect to sp^(2) -hybrid carbon should have at least one hydrogen. Hyperconjugation are of three types: (i) sigma(C-H),pi -conjugation, (ii) sigma(C-H), positive charge conjugation, (iii) sigma(C-H) , odd electron conjugation. The hyperconjugation may be represented as, Number of resonating structures due to hyperconjugation =(n+1) , where n is the numebr of alpha -hydrogen. Greater is the number of such forms, more is the stability of the species under consideration. Which of the following free redicals will not show the phenomena of hyperconjugation?

A2Z-SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY-Section D - Chapter End Test
  1. Which of the following alkenes will show maximum number of hyperconjug...

    Text Solution

    |

  2. Arrange the following comounds in increasing order of length of their ...

    Text Solution

    |

  3. The order of heat of hydrogenation in following compounds is:

    Text Solution

    |

  4. S(N)1 reaction is faster in

    Text Solution

    |

  5. Which compound would be least soluble in water?

    Text Solution

    |

  6. Among the following compound which can be dehydrated very easily is :

    Text Solution

    |

  7. Which of the follwing is not the characteristic of the mechanism of fr...

    Text Solution

    |

  8. Find the strongest acid among the following compound

    Text Solution

    |

  9. Among the following the dissociation constant is highest

    Text Solution

    |

  10. Which one of the following compounds is most acidic

    Text Solution

    |

  11. The optically active tartaric acid is named as D-(+)- tartaric acid be...

    Text Solution

    |

  12. Among the following compounds (I-II) the correct order of reaction wit...

    Text Solution

    |

  13. The following reaction is described as

    Text Solution

    |

  14. Which of the following is the most stable cation?

    Text Solution

    |

  15. The observed dipole moment of nitromethane is highly than the dipole m...

    Text Solution

    |

  16. Dehydrohalogenation in presence of OH^(-) is correct represented by

    Text Solution

    |

  17. Among the following the aromatic compound is

    Text Solution

    |

  18. Which of the following compounds are not arranged in order of decreasi...

    Text Solution

    |

  19. Most stable carbonium ion is :

    Text Solution

    |

  20. Which one of the following species is most stable

    Text Solution

    |

  21. Which of the following gives most stable carbocation by dehydration

    Text Solution

    |