Home
Class 11
CHEMISTRY
Choose the strongest base among the foll...

Choose the strongest base among the following:

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine the strongest base among the given options, we need to analyze the availability of the lone pairs of electrons on the nitrogen atoms in each structure. The more available the lone pair, the stronger the base. ### Step-by-Step Solution: 1. **Identify the Structures**: - Let's denote the compounds as A, B, C, and D. Each compound has a nitrogen atom with a lone pair. 2. **Analyze Resonance Effects**: - **Compound A**: The nitrogen's lone pair can participate in resonance with the aromatic ring, making it less available for protonation. - **Compound B**: Similar to A, the lone pair on nitrogen can also participate in resonance with the ring, reducing its basicity. - **Compound C**: The lone pair on nitrogen can participate in resonance, but it is slightly more available than in A and B due to the structure. - **Compound D**: The lone pair on nitrogen is not involved in resonance with any ring or double bond, making it fully available for donation. 3. **Compare Basicity**: - Since the lone pairs in compounds A, B, and C are involved in resonance, they are less available for bonding with protons (H⁺). - In contrast, the lone pair in compound D is not involved in resonance, making it the most available for protonation. 4. **Conclusion**: - Based on the analysis, compound D has the most available lone pair and is therefore the strongest base among the options provided. ### Final Answer: The strongest base among the given options is **D**.

To determine the strongest base among the given options, we need to analyze the availability of the lone pairs of electrons on the nitrogen atoms in each structure. The more available the lone pair, the stronger the base. ### Step-by-Step Solution: 1. **Identify the Structures**: - Let's denote the compounds as A, B, C, and D. Each compound has a nitrogen atom with a lone pair. 2. **Analyze Resonance Effects**: ...
Promotional Banner

Topper's Solved these Questions

  • SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY

    A2Z|Exercise Bond Fission, Reagents, Reactive Intermediates And Their Stability|31 Videos
  • SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY

    A2Z|Exercise Structure Isomerism|28 Videos
  • SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY

    A2Z|Exercise Section D - Chapter End Test|60 Videos
  • SOME BASIC CONCEPTS OF CHEMISTRY

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • STATES OF MATTER

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

The strongest base among the following is

The strongest base among the following is

The strongest base among the following is

The strongest base among the following is

The strongest base among the following is

The strongest base among the following is

A2Z-SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY-Acid And Basic Strength
  1. Out of the following compunds, which will have a zero diopole moment?

    Text Solution

    |

  2. Arrange the following in increasing order of basic strength

    Text Solution

    |

  3. Choose the strongest base among the following:

    Text Solution

    |

  4. Which of the following has lowest melting point?

    Text Solution

    |

  5. Select the basic strength order of following molecules

    Text Solution

    |

  6. What is formed in the above reaction?

    Text Solution

    |

  7. Consider thiol anion (RS^(Theta)) and alkoxy anion (RO^(Theta)). Which...

    Text Solution

    |

  8. The correct basic strength order of the following anions is:

    Text Solution

    |

  9. Which of the following has the most acidic hydrogen ?

    Text Solution

    |

  10. Which of the following cannot be a base?

    Text Solution

    |

  11. Arrange above phenol in increasing order of pK(a) value:

    Text Solution

    |

  12. Arrange the following compounds in decreasing order of their acidic st...

    Text Solution

    |

  13. Which compound would be least soluble in water?

    Text Solution

    |

  14. Identify the correct order of boiling points of the following compound...

    Text Solution

    |

  15. Most acidic hydrogen is present in:

    Text Solution

    |

  16. The decreasing order of electron density on the ring is:

    Text Solution

    |

  17. The correct order of increasing basicity of the given conjugate bases ...

    Text Solution

    |

  18. Among the following compounds, the most acid is:

    Text Solution

    |

  19. Correct dipole moment order is: underset((p))(CH(2)=CH-Cl),underset(...

    Text Solution

    |

  20. Which of the following compound is the strongest base?

    Text Solution

    |