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The correct basic strength order of the ...

The correct basic strength order of the following anions is:

A

`CH_(3)-overset(Θ)(CH_(2)) gt overset(Θ)(NH_(2)) gt CH_(2)=overset(Θ)(CH) gt CH-=overset(Θ)(C ) gt Hoverset(Θ)(O) gt overset(Θ)(F)`

B

`overset(Θ)(NH_(2)) gt CH_(3)-overset(Θ)(CH_(2)) gt CH_(2)=overset(Θ)(CH) gt CH-=overset(Θ)(C ) gt overset(Θ)(F) gt H overset(Θ)(O)`

C

`CH_(3)-overset(Θ)(C)H_(2) gt CH_(2)=overset(Θ)(CH) gt overset(Θ)(N)H_(2) gt CH-=overset(Θ)(C ) gt Hoverset(Θ)(O) gt overset(Θ)(F)`

D

`overset(Θ)(F) gt Hoverset(Θ)(O) gt CH-=overset(Θ)(C ) gt CH_(2)=overset(Θ)(C)H gt overset(Θ)(N)H_(2) gt CH_(3)-overset(Θ)(CH_(2))

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The correct Answer is:
To determine the correct basic strength order of the given anions, we need to analyze the stability of each anion. The less stable the anion, the stronger the base it will be, as it will more readily donate its electrons. Here’s a step-by-step breakdown of the reasoning: ### Step 1: Identify the Anions Let's assume the anions in question are: 1. \( F^- \) (Fluoride) 2. \( OH^- \) (Hydroxide) 3. \( CH_3^- \) (Methyl anion) 4. \( NH_2^- \) (Amide anion) 5. \( CH_2=CH^- \) (Vinyl anion) ### Step 2: Analyze the Stability of Each Anion 1. **Fluoride (\( F^- \))**: - Highly electronegative, holds onto its electrons tightly. - **Stability**: Very stable due to high electronegativity. - **Basic strength**: Weak base. 2. **Hydroxide (\( OH^- \))**: - Less electronegative than fluoride but still holds onto the negative charge fairly well. - **Stability**: Moderately stable. - **Basic strength**: Moderate base. 3. **Amide (\( NH_2^- \))**: - Nitrogen is less electronegative than oxygen. - **Stability**: Less stable than hydroxide, can donate its electrons more readily. - **Basic strength**: Stronger base than hydroxide. 4. **Vinyl anion (\( CH_2=CH^- \))**: - SP2 hybridized, less stable than amide but more stable than methyl. - **Stability**: Less stable than \( NH_2^- \). - **Basic strength**: Strong base. 5. **Methyl anion (\( CH_3^- \))**: - SP3 hybridized, least electronegative, and least stable. - **Stability**: Least stable, readily donates its electrons. - **Basic strength**: Strongest base. ### Step 3: Order the Basic Strengths Based on the stability analysis: - **Weakest base**: \( F^- \) (most stable) - **Next**: \( OH^- \) - **Next**: \( NH_2^- \) - **Next**: \( CH_2=CH^- \) - **Strongest base**: \( CH_3^- \) (least stable) ### Final Order of Basic Strength The order of basic strength from weakest to strongest is: \[ F^- < OH^- < NH_2^- < CH_2=CH^- < CH_3^- \] ### Conclusion Thus, the correct basic strength order of the anions is: - **C part** (assuming C part corresponds to the order derived).

To determine the correct basic strength order of the given anions, we need to analyze the stability of each anion. The less stable the anion, the stronger the base it will be, as it will more readily donate its electrons. Here’s a step-by-step breakdown of the reasoning: ### Step 1: Identify the Anions Let's assume the anions in question are: 1. \( F^- \) (Fluoride) 2. \( OH^- \) (Hydroxide) 3. \( CH_3^- \) (Methyl anion) 4. \( NH_2^- \) (Amide anion) ...
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A2Z-SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY-Acid And Basic Strength
  1. Choose the strongest base among the following:

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  2. Which of the following has lowest melting point?

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  3. Select the basic strength order of following molecules

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  4. What is formed in the above reaction?

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  5. Consider thiol anion (RS^(Theta)) and alkoxy anion (RO^(Theta)). Which...

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  6. The correct basic strength order of the following anions is:

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  7. Which of the following has the most acidic hydrogen ?

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  8. Which of the following cannot be a base?

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  9. Arrange above phenol in increasing order of pK(a) value:

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  10. Arrange the following compounds in decreasing order of their acidic st...

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  11. Which compound would be least soluble in water?

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  12. Identify the correct order of boiling points of the following compound...

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  13. Most acidic hydrogen is present in:

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  14. The decreasing order of electron density on the ring is:

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  15. The correct order of increasing basicity of the given conjugate bases ...

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  16. Among the following compounds, the most acid is:

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  17. Correct dipole moment order is: underset((p))(CH(2)=CH-Cl),underset(...

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  18. Which of the following compound is the strongest base?

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  19. Arrange in the order of increasing acidic strengths.

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  20. Find more basic between following pairs of compounds? underset(...

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