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Among the following compounds, one that ...

Among the following compounds, one that will not shown keto-enol tautomerism is

A

B

C

D

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The correct Answer is:
To determine which compound among the given options does not show keto-enol tautomerism, we need to analyze the presence of alpha-hydrogens in each compound. Keto-enol tautomerism occurs when there is an alpha-hydrogen available for the tautomerization process. ### Step-by-Step Solution: 1. **Identify the Compounds**: First, we need to examine the structures of the compounds provided in the question. Let's denote them as A, B, C, and D. 2. **Locate the Alpha Carbons**: For each compound, identify the alpha carbons. An alpha carbon is the carbon atom adjacent to the carbonyl group (C=O). 3. **Check for Alpha-Hydrogens**: Next, check if there are any alpha-hydrogens attached to the alpha carbons. The presence of at least one alpha-hydrogen is essential for keto-enol tautomerism to occur. 4. **Analyze Compound B**: In the analysis, it was noted that compound B does not have any alpha-hydrogens available. This means that it cannot undergo keto-enol tautomerism. 5. **Consider Stability of Tautomerization**: For the other compounds (A, C, and D), they all have alpha-hydrogens, and thus, they can undergo tautomerization. However, it was also mentioned that in certain cases (like with a bridgehead carbon), the formation of an enol may lead to instability, but this does not prevent tautomerism from occurring. 6. **Conclusion**: Based on the analysis, the compound that does not show keto-enol tautomerism is compound B, as it lacks alpha-hydrogens. ### Final Answer: The compound that will not show keto-enol tautomerism is **Compound B**.

To determine which compound among the given options does not show keto-enol tautomerism, we need to analyze the presence of alpha-hydrogens in each compound. Keto-enol tautomerism occurs when there is an alpha-hydrogen available for the tautomerization process. ### Step-by-Step Solution: 1. **Identify the Compounds**: First, we need to examine the structures of the compounds provided in the question. Let's denote them as A, B, C, and D. 2. **Locate the Alpha Carbons**: For each compound, identify the alpha carbons. An alpha carbon is the carbon atom adjacent to the carbonyl group (C=O). ...
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Knowledge Check

  • Among the following compounds, the one which does not show ket-enol tautomerism is :

    A
    B
    C
    D
  • Keto-enol tautomerism is shown by

    A
    `C_6 H_5 CHO`
    B
    `C_6 H_5 COCH_3`
    C
    `C_6 H_5 COC_6 H_5`
    D
    `C_6 H_5 COCH_2 CO CH_3`
  • Among the following compounds having highest enol content.

    A
    `CH_(3)COOCH_(3)`
    B
    `CH_(3)COCH_(3)`
    C
    `CH_(3)-underset(O)underset(||)C-CH_(2)-CHO`
    D
    `CH_(3)-underset(O)underset(||)C-CH_(2)-underset(O)underset(||)C-OCH_(3)`
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