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Which of the following compound is optic...

Which of the following compound is optically inactive?

A

`CH_(3)-CH_(2)-overset(OH)overset(|)(CH)-CH_(3)`

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds is optically inactive, we need to identify whether each compound has a stereogenic center (chiral carbon). A compound is optically inactive if it does not have any chiral centers. ### Step-by-Step Solution: 1. **Identify the Compounds**: We need to analyze each compound provided in the question to check for chiral centers. 2. **Analyze Compound A**: - Compound A has four different groups attached to a carbon atom: ethyl, methyl, hydrogen, and hydroxyl (OH). - Since all four groups are different, this carbon is a chiral center. - **Conclusion**: Compound A is optically active. 3. **Analyze Compound B**: - Compound B has one hydrogen, one A group, one A group, and one methyl (CS3). - Here, two groups are identical (the two A groups), which means this carbon does not have four different groups. - **Conclusion**: Compound B is not a chiral center and is optically inactive. 4. **Analyze Compound C**: - Compound C has a carbon attached to hydrogen (H), chlorine (Cl), and two identical groups. - Since there are two identical groups, this carbon is not a chiral center. - **Conclusion**: Compound C is optically inactive. 5. **Analyze Compound D**: - Compound D has one hydrogen, one methyl (CS3), and one A group. - All three groups are different, making this carbon a chiral center. - **Conclusion**: Compound D is optically active. 6. **Final Conclusion**: - From the analysis, we find that Compound B and Compound C do not have chiral centers and are therefore optically inactive. However, since the question asks for one compound, we can conclude that **Compound B** is the one explicitly mentioned as optically inactive. ### Final Answer: **Compound B is optically inactive.**

To determine which of the given compounds is optically inactive, we need to identify whether each compound has a stereogenic center (chiral carbon). A compound is optically inactive if it does not have any chiral centers. ### Step-by-Step Solution: 1. **Identify the Compounds**: We need to analyze each compound provided in the question to check for chiral centers. 2. **Analyze Compound A**: - Compound A has four different groups attached to a carbon atom: ethyl, methyl, hydrogen, and hydroxyl (OH). ...
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Knowledge Check

  • Presence of chiral center is not an essential condition to show optical isomerism. Essential condition is, compound should show non-superimposable mirror image. Allenes do not contain chiral center but show optical isomerism when different groups are attached on double bonded carbonds. Biphenyls alos show optical isomerism when both rings are perpendicular to each other and any ring should not contain plane of symmetry. Which of the following compounds is optically inactive?

    A
    B
    C
    D
  • Which of the following compound is optically active

    A
    `C_(2)H_(5)-OH`
    B
    `(CH_(3))_(2)CHCH_(3)-Cl`
    C
    `CH_(3)-CHClC_(2)H_(5)`
    D
    `C Cl_(2)F_(2)`
  • Which of the following compounds is optically active?

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    `CH_(3) - CH_(2) - CH_(2) OH`
    B
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    `CH_(3) underset(Cl)underset(|)(CH) CH_(3)`
    D
    `CH_(3) - CH_(2) - CH_(3)`
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