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Assertion: Enol form of cyclohexane-1,3,...

Assertion: Enol form of cyclohexane-`1,3,5`-trione is more stable than its keto-form.
Reason: It does not contain a-hydrogen atoms.

A

If both assertion and reason are true and the reason is the correct explanation of the assertion.

B

If both assertion and reason are true and the reason is the correct explanations of the assertion

C

If assertion is true but reason is false.

D

If assertion is false but reason is true.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that the enol form of cyclohexane-1,3,5-trione is more stable than its keto form. **Hint:** Consider the general stability of keto and enol forms in organic compounds. ### Step 2: Analyze the Structure of Cyclohexane-1,3,5-trione Cyclohexane-1,3,5-trione has three carbonyl (C=O) groups located at positions 1, 3, and 5 of the cyclohexane ring. **Hint:** Draw the structure of cyclohexane-1,3,5-trione to visualize the carbonyl groups and their positions. ### Step 3: Consider the Enol Form The enol form of cyclohexane-1,3,5-trione would involve the conversion of one of the carbonyl groups to an alcohol (C-OH) group. **Hint:** Remember that enolization involves the presence of alpha hydrogen atoms for stability. ### Step 4: Evaluate Stability Keto forms are generally more stable than enol forms because of the stronger C=O double bond compared to the C-OH bond in enols. In this case, the assertion that the enol form is more stable is incorrect. **Hint:** Recall that keto-enol tautomerism favors the keto form due to the stability of carbonyl groups. ### Step 5: Analyze the Reason The reason states that the enol form does not contain alpha-hydrogen atoms. This is true, as the carbonyl groups in cyclohexane-1,3,5-trione do not have any hydrogen atoms attached to the carbon adjacent to them. **Hint:** Consider the role of alpha-hydrogens in the stability of enol forms. ### Step 6: Conclusion Since the assertion is false (the enol form is not more stable than the keto form) but the reason is true (there are no alpha-hydrogens), the correct answer is that the assertion is false and the reason is true. **Final Answer:** D) Assertion is false, but reason is true.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that the enol form of cyclohexane-1,3,5-trione is more stable than its keto form. **Hint:** Consider the general stability of keto and enol forms in organic compounds. ### Step 2: Analyze the Structure of Cyclohexane-1,3,5-trione ...
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