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Among the following the dissociation con...

Among the following the dissociation constant is highest

A

`C_(6)H_(5)OH`

B

`C_(6)H_(5)CH_(2)OH`

C

`CH_(3)C-=CH`

D

`CH_(3)NH_(3)^(+)Cl^(-)`

Text Solution

Verified by Experts

The correct Answer is:
D

Dissociation of proton from `CH_(3)-overset(+)(H_(3))Cl^(-)` is very difficult due to `-I` effect of `Cl^(-)` and `N^(+)` while in `C_(6)H_(5)CH` due easily, similarly due to `H`-bonding in `C_(6)H_(5)CH_(2)OH` it can be eliminated and `CH_(3)-=CH` shows aacidic character by triple bond by which proton can be dissociation.
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A2Z-SOME BASIC PRINCIPALS OF ORGANIC CHEMISTRY-Section D - Chapter End Test
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