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A gas consisting of rigid diatomic molec...

A gas consisting of rigid diatomic molecules was expanded in a polytropic process so that the rate of collisions of the molecules against the vessel's wall did not change. Find the molar heat capacity of the gas in this process.

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If `alpha` is the polytropic index then
`pV^alpha =` constant, `TV^(alpha -1) =` constant
Now `(v')/(v') = (n')/(n) (lt v' gt)/(lt v gt) = (V)/(V') sqrt((T')/(T)) = (VT^(-1//2))/(V' T'^(-1//2)) = 1`
Hence `(1)/(alpha - 1) = -(1)/(2)`or `alpha = -1`
Then `C = (iR)/(2) + ( R)/(2) = 3 R`.
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