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An optically pure compound A, gave an [a...

An optically pure compound `A,` gave an `[alpha]_(D)^(25)=+30^(@),` while a mixture of `A` and its enantiomer `B`, gave `[alpha]_(D)^(25)=+15^(@),` . The ratio of `A` to `B` in the mixture is

A

1 to 3

B

3 to 1

C

1 to 2

D

2 to 1

Text Solution

Verified by Experts

The correct Answer is:
B

`(15)/(30)xx100=50`
Thus the mixture is 50% opticaaly pure. Hence the amount of
`A=50+25=75 B=0+25=25`
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