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Markovnikov's rule is empirical but may ...

Markovnikov's rule is empirical but may be explained theoretically on the basis that the addition occurs by a

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Vladimir Markovnikov rule: Alkenes undergo electrophilic addition reactions. It is triggered by the acid acting as a electrophile toward pi -electrons of the double bond. Markovnikov's rule states that when an unsymmetrically substituted alkene reacts with a hydrogen halide, the hydrogen atom adds to the carbon that has the greater number of hydrogen, e.g., Which of the following is most reactive toward Markovnikov addition?