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A5% solution of cane sugar (molar mass =...

A`5%` solution of cane sugar (molar mass =`342`)is isotonic with `1%`of a solution of an known solute.The molar mass of unknown solute in g/mol is

A

`136.2`

B

`171.2`

C

`68.4`

D

`34.2`

Text Solution

Verified by Experts

The correct Answer is:
C

Two solution are said to be isotonic ,they have the same molar concentration,Therefore .
Concentration of cane sugar
=Concentration of `[C_(12)H_(22)O_(11)]`
As unknown solute`[X]`
for `C_(12)H_(22)O_(11)`,
concentration `=(5g)/(100cm^(3))=50//L=(50)/(342)molL^(-1)`
`[:. "Molar mass of" C_(12)H_(22)O_(11)=342g mol^(-1)]` for unknown substance X,
concentration ` =(1g)/(100cm^(3))=10g//L=(10)/(M)molL^(-1)`
Hence, `(50)/(342)molL^(-1)=(10)/(M)molL^(-1)`
`rArr M=(342xx10)/(50)`
`rArrM=68.4g molL^(-1)`
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