Home
Class 12
CHEMISTRY
One Faraday of electricity when passed t...

One Faraday of electricity when passed through a solution of copper sulphate deposits .

A

1 mloe of Cu

B

`1` g ewuivalent of Cu

C

`1` g ewiovalent of Cu

D

`1` molecule of Cu

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of how much copper is deposited when 1 Faraday of electricity is passed through a solution of copper sulfate (CuSO4), we can follow these steps: ### Step-by-Step Solution: 1. **Understand Faraday's Law of Electrolysis**: Faraday's law states that the amount of substance deposited or liberated during electrolysis is directly proportional to the quantity of electricity passed through the solution. The relationship can be expressed as: \[ W = Z \cdot Q \] where: - \( W \) = mass of the substance deposited (in grams) - \( Z \) = electrochemical equivalent of the substance (in grams per Faraday) - \( Q \) = total electric charge passed (in Faradays) 2. **Determine the Electrochemical Equivalent (Z) for Copper**: For copper (Cu), the valency is +2 (as it forms Cu²⁺ ions in solution). The equivalent weight (E) of copper can be calculated using the formula: \[ E = \frac{M}{n} \] where: - \( M \) = molar mass of copper (approximately 63.5 g/mol) - \( n \) = number of electrons transferred per ion (which is 2 for Cu²⁺) Thus, the equivalent weight of copper is: \[ E = \frac{63.5 \, \text{g/mol}}{2} = 31.75 \, \text{g/equiv} \] 3. **Calculate the Amount of Copper Deposited**: When 1 Faraday of charge is passed through the solution, we can substitute \( Q = 1 \) Faraday into the equation: \[ W = Z \cdot Q \] Since \( Z \) for copper is equal to its equivalent weight (31.75 g/equiv), we have: \[ W = 31.75 \, \text{g/equiv} \cdot 1 \, \text{Faraday} = 31.75 \, \text{g} \] 4. **Conclusion**: Therefore, when 1 Faraday of electricity is passed through a solution of copper sulfate, approximately 31.75 grams of copper will be deposited. ### Final Answer: **31.75 grams of copper will be deposited.** ---

To solve the problem of how much copper is deposited when 1 Faraday of electricity is passed through a solution of copper sulfate (CuSO4), we can follow these steps: ### Step-by-Step Solution: 1. **Understand Faraday's Law of Electrolysis**: Faraday's law states that the amount of substance deposited or liberated during electrolysis is directly proportional to the quantity of electricity passed through the solution. The relationship can be expressed as: \[ W = Z \cdot Q ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    A2Z|Exercise Fuel Cell And Batteries|10 Videos
  • ELECTROCHEMISTRY

    A2Z|Exercise Construction And Working Of A Cell, Electrochemical Series And Its Applications|91 Videos
  • ELECTROCHEMISTRY

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • COORDINATION COMPOUNDS

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF METALS

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

Four Faraday of electricity is passed through solution of Ferrous sulphate . The mass of iron (At. Wt. 56) deposited at cathode in terms of grams is

A current was passed for two hour through a solution of an acid that liberated 11.2 litre of oxygen at NTP at anode. What will be the amount of copper deposited at the cathode by the same current when passed through a solution of copper sulphate for the same time?

When 2 Faraday of electricity is passed in an aqueous solution of cupric sulphate, the amount of copper deposited on cathode is

Three Faradays of electricity was passed through an aqueous solution of Magnesium bromide. The weight of Magnesium metal deposited at the cathode in grams is

One faraday of electricicy is passed through aqueous solution of sodium chloride. It produces

A2Z-ELECTROCHEMISTRY-Electrosis And Faraday'S Laws
  1. A certain current liberates 0.5g of hydrogen in 2 hours. How many gra...

    Text Solution

    |

  2. On passing 0.1 F of electricity through aluminimum chloride, the amoun...

    Text Solution

    |

  3. One Faraday of electricity when passed through a solution of copper su...

    Text Solution

    |

  4. A current of 2 A was passed for 1 h through a solution of CuSO4. 0.237...

    Text Solution

    |

  5. To deposit 0.6354 g of copper by electrolysis of aqueous cupric sulpba...

    Text Solution

    |

  6. What is the amount of chlorine evoled when 2 amperes of current is pas...

    Text Solution

    |

  7. 96500 culombs of electric current liberates from CuSO4 solution.

    Text Solution

    |

  8. Three faradays of electricity are passed through molten Al2O3 aqueous ...

    Text Solution

    |

  9. When electricity is passed through a solution of AlCl(3) and 13.5g of ...

    Text Solution

    |

  10. In an electroplating experiment m g of silver is deposited, whe 4 ampe...

    Text Solution

    |

  11. 2.5 F of electricity is passed through a CuSO4 solution. The number of...

    Text Solution

    |

  12. The amount of silver deposited by passing 241. 25 C of current through...

    Text Solution

    |

  13. Charge required to liberated 11.5 g sodium is .

    Text Solution

    |

  14. In electrolysis of dilute H2SO4 using platinum electrodes .

    Text Solution

    |

  15. A solution containing 1 mol per litre of each Cu(NO(3))(2), AgNO(3), ...

    Text Solution

    |

  16. Aluminium oxide may be electorlysed at 1000^@C to furnish aluminim met...

    Text Solution

    |

  17. During electrolysis of an aqeous solution of sodium sulphate if 2.4 Lo...

    Text Solution

    |

  18. A current of strength 2.5 A was passed through CuSO4 solution for 6 ...

    Text Solution

    |

  19. When electricity is passed through a solution of AlCl(3) and 13.5g of ...

    Text Solution

    |

  20. A current of 0.75 A is passed through an acidic solution of CuSO4 for ...

    Text Solution

    |