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The standard potentials at 25^@C for the...

The standard potentials at `25^@C` for the following half reactions are given against them
` Zn^(2+) +2e^(-) rarr Zn, E^0 =-0 . 762 V `
`Mg^(2+) +2e^(-) rarr Mg, =- 2.37 V`.
When zinc dust is added to a solution of magnesium chloride .`

A

No reaction will take place

B

Zinc chloride is formed

C

Zinc dissolve in solution

D

Magnesium is preciptiated

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The correct Answer is:
To solve the problem, we need to analyze the half-reactions and their standard electrode potentials to determine if a reaction will occur when zinc dust is added to a magnesium chloride solution. ### Step-by-Step Solution: 1. **Identify the Half-Reactions**: - The half-reaction for zinc is: \[ \text{Zn}^{2+} + 2e^{-} \rightarrow \text{Zn}, \quad E^{\circ} = -0.762 \, \text{V} \] - The half-reaction for magnesium is: \[ \text{Mg}^{2+} + 2e^{-} \rightarrow \text{Mg}, \quad E^{\circ} = -2.37 \, \text{V} \] 2. **Determine the Oxidation and Reduction**: - When zinc is added to magnesium chloride, zinc will potentially oxidize (lose electrons) and magnesium ions will potentially reduce (gain electrons). - The oxidation reaction can be written as: \[ \text{Zn} \rightarrow \text{Zn}^{2+} + 2e^{-} \] - The reduction reaction can be written as: \[ \text{Mg}^{2+} + 2e^{-} \rightarrow \text{Mg} \] 3. **Calculate the Standard Cell Potential (E°cell)**: - The standard cell potential can be calculated using the formula: \[ E^{\circ}_{\text{cell}} = E^{\circ}_{\text{reduction}} - E^{\circ}_{\text{oxidation}} \] - Here, the reduction potential for magnesium is -2.37 V and the oxidation potential for zinc is +0.762 V (note that we take the negative of the oxidation potential). - Therefore: \[ E^{\circ}_{\text{cell}} = (-2.37) - (-0.762) = -2.37 + 0.762 = -1.608 \, \text{V} \] 4. **Analyze the Result**: - A negative cell potential indicates that the reaction is not spontaneous. This means that zinc cannot oxidize in the presence of magnesium ions. 5. **Conclusion**: - Since the cell potential is negative, no reaction occurs when zinc dust is added to a solution of magnesium chloride. ### Final Answer: No reaction will take place when zinc dust is added to a solution of magnesium chloride because magnesium has a higher tendency to oxidize than zinc.

To solve the problem, we need to analyze the half-reactions and their standard electrode potentials to determine if a reaction will occur when zinc dust is added to a magnesium chloride solution. ### Step-by-Step Solution: 1. **Identify the Half-Reactions**: - The half-reaction for zinc is: \[ \text{Zn}^{2+} + 2e^{-} \rightarrow \text{Zn}, \quad E^{\circ} = -0.762 \, \text{V} ...
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The standerd potential at 25^(@) for the following Half rection is given : Zn^(2+)+2e^(-)toZn,E^(@)=-0.762 V Mg^(2+)+2e^(-)toMg,E^(@)=-2.37 V When Zinc dust is added to the solution of MgCl_(2) .

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A2Z-ELECTROCHEMISTRY-Construction And Working Of A Cell, Electrochemical Series And Its Applications
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  13. In wich of the following electrochemical cell the overall cell reactio...

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  14. Civen E^@ for Cu^(2+) rarr Cu^+ is + 0.15 V and Cu^+ rarr Cu is ...

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  15. Two half cells have reduction potentials -0.76 V and -0.13 V respectiv...

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  16. Consider the following E^@ values . E^(0)((Fe^(3+)//Fe^(2+)) = + 0.77...

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