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Given,{:(E(Fe^(3+) //Fe)^o + 3e Cr E^o ...

Given,`{:(E_(Fe^(3+) //Fe)^o + 3e Cr E^o =- 0.036 V),(E_(Fe^(3+) //Fe)^o =- 0.439 V):}`
The value of standard electrode ptoential for the charge,

A

`(-0.036 -0. 439) V`

B

`(- 0.36 + 0. 439) V`

C

`[3 (- 0.036) +2 (- 0.439) + 2(- 0.439)] V`

D

`[3 (-0.36) - 2 ( - 0. 439) ] V`

Text Solution

Verified by Experts

The correct Answer is:
D

`Fe^(3+) +3e rarr Fe" " DeltaG_1^0 =- 3 F^(-).36) V`
`Fe^(2+) +3e rarr Fe" " DeltaG_0^2 =- 3 F(-0.439) V`
` Fe^(3+) +3e rarr Fe^(2+)" " DeltaG_("net")^@ = DeltaG_1^@- DeltaG_2^@`
or `Delta _("net")^@ =- F (-0.36) -2n (-0.439)] V`
or ` S^@ = [(3 (-0. 36 ) -2 (-0.439)] V`.
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