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The rate of a reaction doubles when its ...

The rate of a reaction doubles when its temperature changes form `300 K` to `310 K`. Activation energy of such a reaction will be:
`(R = 8.314 JK^(-1) mol^(-1) and log 2 = 0.301)`

A

`53.6 JK^(-1) "mol"^(-1)`

B

`48.6 JK^(-1) "mol"^(-1)`

C

`58.5 JK^(-1) "mol"^(-1)`

D

`60.5 JK^(-1) "mol"^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
A

Form Arrhenius equation,
`log` `(k_(2))/(k_(1)) = (-E_(a))/(2.303R)((1)/(T_(2)) - (1)/(T_(1)))`
Given, `(k_(2))/(k_(1)) = 2, T_(2) = 310 K`
`T_(1) = 300 K`
On putting values,
`rArr log 2 = (-E_(a))/(2.303 xx 8.314) ((1)/(310) - (1)/(310))`
`rArr E_(a) = 53603.93 J//mol = 53.6 kJ//mol`
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