Home
Class 12
CHEMISTRY
In a reaction , A + B rarr Product, rate...

In a reaction , `A + B rarr` Product, rate is doubled when the concentration of `B` is doubled, and rate increases by a factor of `8` when the concentration of both the reactants (A and B) are doubled, rate law for the reaction can be written as

A

Rate `= k[A]^(2)[B]`

B

Rate `= k[A][B]`

C

Rate `= k[A][B]^(2)`

D

Rate `= k[A]^(2)[B]^(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the rate law for the reaction \( A + B \rightarrow \text{Product} \) based on the information provided about how the rate changes with varying concentrations of reactants. ### Step-by-Step Solution: 1. **Write the Rate Law Expression**: The rate law for the reaction can be expressed as: \[ \text{Rate} = k[A]^x[B]^y \] where \( k \) is the rate constant, and \( x \) and \( y \) are the orders of the reaction with respect to reactants \( A \) and \( B \) respectively. 2. **Analyze the First Condition**: According to the problem, when the concentration of \( B \) is doubled (from \( [B] \) to \( 2[B] \)), the rate doubles. This can be expressed mathematically as: \[ 2R = k[A]^x[2B]^y \] Simplifying this gives: \[ 2R = k[A]^x \cdot 2^y[B]^y \] Dividing both sides by the original rate \( R = k[A]^x[B]^y \): \[ \frac{2R}{R} = \frac{k[A]^x \cdot 2^y[B]^y}{k[A]^x[B]^y} \] This simplifies to: \[ 2 = 2^y \] From this, we can conclude that: \[ y = 1 \] 3. **Analyze the Second Condition**: The second condition states that when the concentrations of both \( A \) and \( B \) are doubled, the rate increases by a factor of 8. This can be expressed as: \[ 8R = k[2A]^x[2B]^y \] Simplifying this gives: \[ 8R = k \cdot 2^x[A]^x \cdot 2^y[B]^y \] Dividing both sides by \( R \): \[ \frac{8R}{R} = \frac{k \cdot 2^x[A]^x \cdot 2^y[B]^y}{k[A]^x[B]^y} \] This simplifies to: \[ 8 = 2^{x+y} \] Since \( 8 = 2^3 \), we can equate the exponents: \[ x + y = 3 \] 4. **Substitute the Value of \( y \)**: We already found that \( y = 1 \). Substituting this into the equation \( x + y = 3 \): \[ x + 1 = 3 \] Thus, we find: \[ x = 2 \] 5. **Write the Final Rate Law**: Now that we have determined the values of \( x \) and \( y \): \[ x = 2, \quad y = 1 \] The rate law for the reaction can be written as: \[ \text{Rate} = k[A]^2[B]^1 \] or simply: \[ \text{Rate} = k[A]^2[B] \] ### Final Answer: The rate law for the reaction is: \[ \text{Rate} = k[A]^2[B] \]

To solve the problem, we need to determine the rate law for the reaction \( A + B \rightarrow \text{Product} \) based on the information provided about how the rate changes with varying concentrations of reactants. ### Step-by-Step Solution: 1. **Write the Rate Law Expression**: The rate law for the reaction can be expressed as: \[ \text{Rate} = k[A]^x[B]^y ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    A2Z|Exercise AIIMS Questions|24 Videos
  • CHEMICAL KINETICS

    A2Z|Exercise Assertion-Reasoning Questions|6 Videos
  • CHEMICAL KINETICS

    A2Z|Exercise Section B - Assertion Reasoning|21 Videos
  • BIOMOLECULES

    A2Z|Exercise Section D - Chapter End Test|30 Videos
  • COORDINATION COMPOUNDS

    A2Z|Exercise Section D - Chapter End Test|30 Videos

Similar Questions

Explore conceptually related problems

For reaction A + B rarr products, the rate of the reaction was doubled when the concentration of A was doubled. The rate was also doubled when the concentration of both A and B were doubled. Then, order of the reaction with respect to A and B are :

For a reaction 2A rarrB Products , doubling the concentration of B alone doubles the rate and doubling the initial concentration of both the reactants increases the rate by a factor of 8 . The rate law for the reaction is

For the reaction A + 2B to C, the reaction rate is doubled if the concentration of A is doubled , the rate is increased by four times when concentrations of both A and B are increased by four times . The order of the reaction is _______.

A2Z-CHEMICAL KINETICS-AIPMT/NEET Questions
  1. For an endothermic reaction energy of activation is E(a) and enthalpy ...

    Text Solution

    |

  2. The rate of the reaction 2NO+CI(2)rarr 2NOCI is given by the rate ...

    Text Solution

    |

  3. For the reaction N(2)O(5) rarr 2NO(2) + (1)/(2) O(2), the rate of disa...

    Text Solution

    |

  4. During the kinetic study of the reaction 2A +B rarr C + D following ...

    Text Solution

    |

  5. Which one of the following statements for the order of a reaction is i...

    Text Solution

    |

  6. For the reaction N(2)(g)+O(2)(g) hArr 2NO(g), the equilibrium constant...

    Text Solution

    |

  7. 2N(2)O(5) rarr 4NO(2) + O(2) If (-d[N(2)O(5)])/(dt) = k(1)[N(2)O(5)]...

    Text Solution

    |

  8. In a zero-order reaction for every 10^(@) rise of temperature, the rat...

    Text Solution

    |

  9. In a reaction , A + B rarr Product, rate is doubled when the concentra...

    Text Solution

    |

  10. Activation energy (E(a)) and rate constants (k(1) and k(2)) of a chemi...

    Text Solution

    |

  11. What is the activation energy for a reaction if its rate doubles when ...

    Text Solution

    |

  12. A reaction having equal energies of activation for toward and reverse ...

    Text Solution

    |

  13. The activation energy of a reaction can be determined from the slope o...

    Text Solution

    |

  14. When initial concentration of a reactant is doubled in a reaction, its...

    Text Solution

    |

  15. The rate constant of the reaction A rarr B is 0.6 xx 10^(-3) mole per ...

    Text Solution

    |

  16. The addition of a catallystic during a chemical reaction alters which ...

    Text Solution

    |

  17. The rate of a first-order reaction is 0.04 "mol L"^(-1) s^(-1) at 10 s...

    Text Solution

    |

  18. Mechanism of a hypothetical reaction X(2) + Y(2) rarr 2XY is given b...

    Text Solution

    |

  19. A first order reaction has a specific reaction rate of 10^(-2) sec^(-1...

    Text Solution

    |

  20. When initial concentration of the reactant is doubled, the half-life p...

    Text Solution

    |