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If a second order reaction involving a ...

If a second order reaction involving a single reactant in `25%` complete in `20` minutes then what is its half life if initial concentration of the reactant is being made double at the same temperature.

A

`50` min

B

`30` min

C

`60` min

D

`15` min

Text Solution

Verified by Experts

The correct Answer is:
B

`(1)/(C ) - (1)/(C_(0)) = kt` (for `2^(nd)` order reaction)
`(1)/((3)/(4)C_(0)) - (1)/(C_(0)) = k xx 20`
`(1)/((1)/(2)(2C_(0))) - (1)/(2C_(0)) = k xx t_(1//2)`
`rArr ((1)/(3C_(0)))/((1)/(2C_(0))) = (20)/(t_(1//2)) rArr (2)/(3) = (20)/(t_(1//2))`
`rArr t_(1//2) = 30` minutes
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