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Which one of the following chargcterisit...

Which one of the following chargcterisitic is associated with adsorption?

A

`Delta G` and `Delta S` are negative but `Delta H` is positive

B

`Delta G` is negative but `DeltaH` and `Delta` are positive

C

`Delta G, Delta H` and `DeltaS` all are negative

D

`Delta G and DeltaH` are negative but `Delta S` is positive

Text Solution

Verified by Experts

The correct Answer is:
C

According to Gibbs - Helmholtz equation.
`Delta G = Delta H - T Delta S`
Adsorption is spontaneous process,
so `Delta G` = negative
Adsorption is exothermic process, so `Delta H = "negative"`
In adsorption entropy decrease,
`so Delta S =` negative.
so `Delta G , Delta H ` and `Delta S` all are negative.
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