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During the extraction of gold the follow...

During the extraction of gold the following reactions takes place
`Au+CN^(-) +H_(2)Orarr X,Y +ZnrarrY+Au`
Here, `X`and `Y` respectively are

A

`[Au(CN)_(4)]^(2-)`and`[Zn(CN)_(6)]^(4-)`

B

`[Au(CN)_(4)]^(3-)`and`[Zn(CN)_(4)]^(2-)`

C

`[Au(CN)_(4)]^(2-)`and`[Zn(CN)_(4)]^(2-)`

D

`[Au(CN)_(2)]^(-)`and`[Zn(CN)_(4)]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
D

`4Au(s) +8CN^(-)(aq)+2H_(2)O(aq)`
`overset(O_(2))rarr4[Au(CN)_(2)] +4OH^(-)(aq)`
`2[Au(CN)_(2)](q) +Zn(s) rarr [Zn(CN)_(4)]^(2-)(aq) +2Au(s)`
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